Optical Absorption, Stability and Structure of NpO2+ Complexeswith Dicarboxylic Acids
Conference
·
OSTI ID:862345
Complexation of NpO2+ with oxalic acid (OX),2,2'-oxydiacetic acid (ODA), 2,2'-iminodiacetic acid (IDA) and 2,2'-thiodiacetic acid (TDA), has been studied using spectrophotometry in1 M NaClO4. Both the position and the intensity of the absorption band of NpO2+ at 980 nm are affected by the formation of NpO2+/dicarboxylate complexes, providing useful information on the complexation strength, the coordination mode and the structure of the complexes.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Director. Office of Science. Office of Basic EnergySciences
- DOE Contract Number:
- DE-AC02-05CH11231
- OSTI ID:
- 862345
- Report Number(s):
- LBNL-59278; R&D Project: 403006; BnR: KC0302030; TRN: US0600657
- Resource Relation:
- Conference: 2005 MRS Fall Meeting, Boston, MA, November 28 -December 2, 2005
- Country of Publication:
- United States
- Language:
- English
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