skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

Technical Report ·
DOI:https://doi.org/10.2172/860324· OSTI ID:860324

Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this reporting period, we conducted several exposure tests with coated and uncoated coupons including a ''500-h'' test. The first experiment was a 316-h test and was designed to look at the performance of Ti/Ta nitride coatings, which seemed to fare the best in earlier tests. The next experiment was a 112-h test with a range of pure metals and commercially available materials. Its purpose was to help identify those metals that best withstood gasifier environment, and hence should be good ingredients for coatings. Finally, we ran a ''500-h'' test, which was also our milestone, with coupons coated with Ti/Ta nitride or Cr/Al coatings.

Research Organization:
SRI International, Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FC26-03NT41616
OSTI ID:
860324
Country of Publication:
United States
Language:
English