The dependence of natural graphite anode performance on electrode density
Abstract
The effect of electrode density for lithium intercalation and irreversible capacity loss on the natural graphite anode in lithium ion batteries was studied by electrochemical methods. Both the first-cycle reversible and irreversible capacities of the natural graphite anode decreased with an increase in the anode density though compression. The reduction in reversible capacity was attributed to a reduction in the chemical diffusion coefficient for lithium though partially agglomerated particles with a larger stress. For the natural graphite in this study the potentials for Li (de)insertion shifted between the first and second formation cycles and the extent of this shift was dependent on electrode density. The relation between this peak shift and the irreversible capacity loss are probably both due to the decrease in graphite surface area with compression.
- Authors:
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE. Assistant Secretary for Energy Efficiency and Renewable Energy. Office of the FreedomCAR and Vehicle Technologies Program (US)
- OSTI Identifier:
- 836040
- Report Number(s):
- LBNL-54100
R&D Project: 674501; TRN: US200503%%239
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 130; Journal Issue: 1-2; Other Information: Submitted to the Journal of Power Sources: Volume 130, No.1-2; Journal Publication Date: 05/03/2004; PBD: 1 Nov 2003
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; ANODES; CAPACITY; COMPRESSION; DIFFUSION; ELECTRODES; GRAPHITE; LITHIUM; LITHIUM IONS; PERFORMANCE; SURFACE AREA; LITHIUM ION BATTERY INTERCALATION IRREVERSIBLE CAPACITY LOSS NATURAL GRAPHITE ELECTRODE DENSITY
Citation Formats
Shim, Joongpyo, and Striebel, Kathryn A. The dependence of natural graphite anode performance on electrode density. United States: N. p., 2003.
Web.
Shim, Joongpyo, & Striebel, Kathryn A. The dependence of natural graphite anode performance on electrode density. United States.
Shim, Joongpyo, and Striebel, Kathryn A. 2003.
"The dependence of natural graphite anode performance on electrode density". United States. https://www.osti.gov/servlets/purl/836040.
@article{osti_836040,
title = {The dependence of natural graphite anode performance on electrode density},
author = {Shim, Joongpyo and Striebel, Kathryn A},
abstractNote = {The effect of electrode density for lithium intercalation and irreversible capacity loss on the natural graphite anode in lithium ion batteries was studied by electrochemical methods. Both the first-cycle reversible and irreversible capacities of the natural graphite anode decreased with an increase in the anode density though compression. The reduction in reversible capacity was attributed to a reduction in the chemical diffusion coefficient for lithium though partially agglomerated particles with a larger stress. For the natural graphite in this study the potentials for Li (de)insertion shifted between the first and second formation cycles and the extent of this shift was dependent on electrode density. The relation between this peak shift and the irreversible capacity loss are probably both due to the decrease in graphite surface area with compression.},
doi = {},
url = {https://www.osti.gov/biblio/836040},
journal = {Journal of Power Sources},
number = 1-2,
volume = 130,
place = {United States},
year = {Sat Nov 01 00:00:00 EST 2003},
month = {Sat Nov 01 00:00:00 EST 2003}
}