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Title: UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION

Abstract

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.

Authors:
Publication Date:
Research Org.:
Velocys (US)
Sponsoring Org.:
(US)
OSTI Identifier:
825287
DOE Contract Number:  
FC26-03NT41905
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 1 Jan 2004
Country of Publication:
United States
Language:
English
Subject:
03 NATURAL GAS; 01 COAL, LIGNITE, AND PEAT; ADSORBENTS; ADSORPTION; CAPACITY; CARBON; COAL MINES; DESIGN; EVALUATION; METHANE; MIXTURES; NATURAL GAS; NITROGEN; PIPELINES; SCHEDULES; VALIDATION; ZEOLITES

Citation Formats

Tonkovich, Anna Lee. UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION. United States: N. p., 2004. Web. doi:10.2172/825287.
Tonkovich, Anna Lee. UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION. United States. https://doi.org/10.2172/825287
Tonkovich, Anna Lee. 2004. "UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION". United States. https://doi.org/10.2172/825287. https://www.osti.gov/servlets/purl/825287.
@article{osti_825287,
title = {UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION},
author = {Tonkovich, Anna Lee},
abstractNote = {The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.},
doi = {10.2172/825287},
url = {https://www.osti.gov/biblio/825287}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2004},
month = {Thu Jan 01 00:00:00 EST 2004}
}