IMPERMEABLE THIN AL2O3 OVERLAY FOR TBC PROTECTION FROM SULFATE AND VANADATE ATTACK IN GAS TURBINES
To improve the hot corrosion resistance of YSZ thermal barrier coatings, a 25 {micro}m and a 2 {micro}m thick Al{sub 2}O{sub 3} overlay were deposited by HVOF thermal spray and by sol-gel coating method, respectively, onto to the surface of YSZ coating. Indenter test was employed to investigate the spalling of YSZ with and without Al{sub 2}O{sub 3} overlay after hot corrosion. The results showed that Al{sub 2}O{sub 3} overlay acted as a barrier against the infiltration of the molten salt into the YSZ coating during exposure, thus significantly reduced the amount of M-phase of ZrO{sub 2} in YSZ coating. However, a thick Al{sub 2}O{sub 3} overlay was harmful for TBC by increasing compressive stress which causes crack and spalling of YSZ coating. As a result, a dense and thin Al{sub 2}O{sub 3} overlay is critical for simultaneously preventing YSZ from hot corrosion and spalling. In the next reporting period, we will measure or calculate the residue stress within Al{sub 2}O{sub 3} overlay and YSZ coating to study the mechanism of effect of Al{sub 2}O{sub 3} overlay on spalling of YSZ coating.
- Research Organization:
- University of Pittsburgh (US)
- Sponsoring Organization:
- (US)
- DOE Contract Number:
- FC26-01NT41189
- OSTI ID:
- 822683
- Resource Relation:
- Other Information: PBD: 16 Dec 2003
- Country of Publication:
- United States
- Language:
- English
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IMPERMEABLE THIN Al{sub 2}O{sub 3} OVERLAY FOR TBC PROTECTION FROM SULFATE AND VANADATE ATTACK IN GAS TURBINES
IMPERMEABLE THIN Al{sub 2}O{sub 3} OVERLAY FOR TBC PROTECTION FROM SULFATE AND VANADATE ATTACK IN GAS TURBINES