Bioorganometallic Chemistry, Part 15. A novel molecular recognition process of host, trans-[Cp*Rh({eta}{sup 1}(N3)-1-methylcytosine)({mu}-OH)]{sub 2} (OTf){sub 2}, with l-aromatic amino acid guests: selective hydrogen bonding to the {mu}-OH groups and the 1-methylcytosine ligands
Journal Article
·
· Journal of Organometallic Chemistry
OSTI ID:816211
The {sup 1}H-NMR and computer docking experiments have elucidated a novel molecular recognition process of host, trans-[Cp*Rh({eta}{sup 1}(Ne)-1-methylcytosine)({mu}-OH)]{sub 2}(OTf){sub 2} (1), with L-aromatic amino acids, which is predicated on a selective hydrogen bonding regime of the NH{sub 3}{sup +} of the amino acid to one of the Rh-{mu}-OH groups, as well as to a C{double_bond}O group of one of the other 1-methycytosine ligands, while the COO{sup -} H-bonds to an NH{sub 2} of the other 1-methycytosine ligand.
- Research Organization:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Organization:
- USDOE Laboratory Directed Research and Development (US)
- DOE Contract Number:
- AC03-76SF00098
- OSTI ID:
- 816211
- Report Number(s):
- LBNL-51772; JORCAI; R&D Project: 470039; TRN: US200320%%317
- Journal Information:
- Journal of Organometallic Chemistry, Vol. 668, Issue 1-2; Other Information: Journal Publication Date: 2/17/2003; PBD: 1 Nov 2002; ISSN 0022-368X
- Country of Publication:
- United States
- Language:
- English
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