Metal alkoxides: templates for organometallic chemistry and catalysis. Final technical report on DE FG 02-86ER13570
The physical properties and chemical reactivities of a series of alkoxide, fluoroalkoxide and thiolate compounds of molybdenum and tungsten having M{triple_bond}M or M{triple_bond}N bonds have been examined which reveal the influence of the pi-donor properties of the ligands: RO > R{sub f}O{approx}RS. Single-site metal alkoxide catalysts for the ring-opening polymerization of lactides have been prepared for the metals magnesium, zinc, and aluminum.
- Research Organization:
- Indiana University, Bloomington, IN (US)
- Sponsoring Organization:
- USDOE Office of Energy Research (ER) (US)
- DOE Contract Number:
- FG02-86ER13570
- OSTI ID:
- 808502
- Resource Relation:
- Other Information: PBD: 1 Nov 2002; PBD: 1 Nov 2002
- Country of Publication:
- United States
- Language:
- English
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