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Title: OXYGEN TRANSPORT CERAMIC MEMBRANES

Technical Report ·
DOI:https://doi.org/10.2172/767396· OSTI ID:767396

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Research Organization:
Federal Energy Technology Center Morgantown (FETC-MGN), Morgantown, WV (United States); Federal Energy Technology Center Pittsburgh (FETC-PGH), Pittsburgh, PA (United States)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
FC26-99FT40054
OSTI ID:
767396
Report Number(s):
DE-FC26-99FT40054-01; TRN: AH200123%%180
Resource Relation:
Other Information: PBD: 1 Oct 2000
Country of Publication:
United States
Language:
English

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