Fundamental spectroscopic studies of carbenes and hydrocarbon radicals
Abstract
Determination of bond dissociation energies and heats of formation of hydrocarbon radicals and carbenes requires knowledge of their structures, but this is not provided by standard mass spectrometric studies; what is needed is high-resolution spectroscopy, often best achieved at centimeter and millimeter wavelengths. Nearly 60 reactive organic molecules were investigated in the period from 1988--1998.
- Publication Date:
- Research Org.:
- Harvard College, Cambridge, Massachusetts, USA (US)
- Sponsoring Org.:
- USDOE Office of Energy Research (ER) (US)
- OSTI Identifier:
- 765943
- DOE Contract Number:
- FG02-88ER13912
- Resource Type:
- Technical Report
- Resource Relation:
- Other Information: PBD: 12 Mar 1999
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBENES; HYDROCARBONS; RADICALS; SPECTROSCOPY; WAVELENGTHS; DISSOCIATION HEAT; FORMATION HEAT
Citation Formats
. Fundamental spectroscopic studies of carbenes and hydrocarbon radicals. United States: N. p., 1999.
Web. doi:10.2172/765943.
. Fundamental spectroscopic studies of carbenes and hydrocarbon radicals. United States. https://doi.org/10.2172/765943
. 1999.
"Fundamental spectroscopic studies of carbenes and hydrocarbon radicals". United States. https://doi.org/10.2172/765943. https://www.osti.gov/servlets/purl/765943.
@article{osti_765943,
title = {Fundamental spectroscopic studies of carbenes and hydrocarbon radicals},
author = {},
abstractNote = {Determination of bond dissociation energies and heats of formation of hydrocarbon radicals and carbenes requires knowledge of their structures, but this is not provided by standard mass spectrometric studies; what is needed is high-resolution spectroscopy, often best achieved at centimeter and millimeter wavelengths. Nearly 60 reactive organic molecules were investigated in the period from 1988--1998.},
doi = {10.2172/765943},
url = {https://www.osti.gov/biblio/765943},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Mar 12 00:00:00 EST 1999},
month = {Fri Mar 12 00:00:00 EST 1999}
}
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