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Title: Fundamental spectroscopic studies of carbenes and hydrocarbon radicals

Abstract

Determination of bond dissociation energies and heats of formation of hydrocarbon radicals and carbenes requires knowledge of their structures, but this is not provided by standard mass spectrometric studies; what is needed is high-resolution spectroscopy, often best achieved at centimeter and millimeter wavelengths. Nearly 60 reactive organic molecules were investigated in the period from 1988--1998.

Publication Date:
Research Org.:
Harvard College, Cambridge, Massachusetts, USA (US)
Sponsoring Org.:
USDOE Office of Energy Research (ER) (US)
OSTI Identifier:
765943
DOE Contract Number:  
FG02-88ER13912
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 12 Mar 1999
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBENES; HYDROCARBONS; RADICALS; SPECTROSCOPY; WAVELENGTHS; DISSOCIATION HEAT; FORMATION HEAT

Citation Formats

. Fundamental spectroscopic studies of carbenes and hydrocarbon radicals. United States: N. p., 1999. Web. doi:10.2172/765943.
. Fundamental spectroscopic studies of carbenes and hydrocarbon radicals. United States. https://doi.org/10.2172/765943
. 1999. "Fundamental spectroscopic studies of carbenes and hydrocarbon radicals". United States. https://doi.org/10.2172/765943. https://www.osti.gov/servlets/purl/765943.
@article{osti_765943,
title = {Fundamental spectroscopic studies of carbenes and hydrocarbon radicals},
author = {},
abstractNote = {Determination of bond dissociation energies and heats of formation of hydrocarbon radicals and carbenes requires knowledge of their structures, but this is not provided by standard mass spectrometric studies; what is needed is high-resolution spectroscopy, often best achieved at centimeter and millimeter wavelengths. Nearly 60 reactive organic molecules were investigated in the period from 1988--1998.},
doi = {10.2172/765943},
url = {https://www.osti.gov/biblio/765943}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Mar 12 00:00:00 EST 1999},
month = {Fri Mar 12 00:00:00 EST 1999}
}