Benzene Evolution Rates from Saltstone Prepared with 2X ITP Flowsheet Concentrations of Phenylborates and Heated to 85 Degrees C

Technical Report · Wed Aug 23 00:00:00 EDT 2000

DOI:https://doi.org/10.2172/761148· OSTI ID:761148

Poirier, M R

The Saltstone Facility provides the final treatment and disposal of low level liquid wastes streams. At the Saltstone Facility, the waste is mixed with cement, flyash, and slag to form a grout, which is pumped into large concrete vaults where it cures. The facility started radioactive operations in June 1990. High Level Waste Engineering requested Savannah River Technology Center to determine the effect of TPB and its decomposition products (i.e., 3PB, 2PB, and 1PB) on the saltstone process. Previous testing performed by SRTC determined saltstone benzene evolution rates a function of ITP filtrate composition. Testing by the Thermal Fluids Laboratory has shown at design operation, the temperature in the Z-area vaults could reach 85 degrees Celsius. Saltstone asked SRTC to perform additional testing to determine whether curing at 85 degrees Celsius could change saltstone benzene evolution rates. This document describes the test performed to determine the effect of curing temperature on the benzene evolution rates.

• Research Organization: Savannah River Site (SRS), Aiken, SC (United States)
• Sponsoring Organization: US Department of Energy (US)
• DOE Contract Number: AC09-96SR18500
• OSTI ID: 761148
• Report Number(s): WSRC-TR-99-00155; TRN: US0103482
• Resource Relation: Other Information: PBD: 23 Aug 2000; PBD: 23 Aug 2000
• Country of Publication: United States
• Language: English

Related Subjects

12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
BENZENE
SYNTHESIS
CONCRETES
CURING
DESIGN
FLOWSHEETS
LIQUID WASTES
SAVANNAH RIVER PLANT
SLAGS
PERFORMANCE TESTING
RADIOACTIVE WASTE PROCESSING
ORGANIC BORON COMPOUNDS
LOW-LEVEL RADIOACTIVE WASTES
WASTE FORMS
DECOMPOSITION