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Title: Groundwater Quality Assessment for Waste Management Area U: First Determination

Technical Report ·
DOI:https://doi.org/10.2172/759254· OSTI ID:759254

Waste Management Area U (TWA U) is located in the 200 West Area of the Hanford Site. The area includes the U Tank Farm, which contains 16 single-shell tanks and their ancillary equipment and waste systems. WMA U is regulated under the Resource Conservation and Recovery Act of 1976 (RCRA) as stipulated in 40 CFR Part 265, Subpart F, which is incorporated into the Washington State dangerous waste regulations (WAC 173-303400) by reference. Groundwater monitoring at WMA U has been guided by an interim status indicator evaluation program. As a result of changes in the direction of groundwater flow, background values for the WMA have been recalculated several times during its monitoring history. The most recent recalculation revealed that one of the indicator parameters, specific conductance, exceeded its background value in downgradient well 299-W19-41. This triggered a change from detection monitoring to a groundwater quality assessment program. The major contributors to the higher specific conductance are nonhazardous constituents, such as bicarbonate, calcium, chloride, magnesium, sodium and sulfate. Chromium, nitrate, and technetium-99 are present and are increasing; however, they are significantly below their drinking water standards. The objective of this study is to determine whether the increased concentrations of chromium, nitrate, and technetium-99 in groundwater are from WMA U or from an upgradient source. Interpretation of groundwater monitoring data indicates that both the nonhazardous constituents causing elevated specific conductance in groundwater and the tank waste constituents present in groundwater at the WMA are a result of surface water infiltration in the southern portion of the WMA. There is evidence that both upgradient and WMA sources contribute to the nitrate concentrations that were detected. There is no indication of an upgradient source for the chromium and technetium-99 that was detected. Therefore, a source of contamination appears to reside in the southern portion of WMA U.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
AC06-76RL01830
OSTI ID:
759254
Report Number(s):
PNNL-13282; R&D Project: 28023; TRN: US0004500
Resource Relation:
Other Information: PBD: 4 Aug 2000
Country of Publication:
United States
Language:
English