Solvated electrons formed in methanol cluster in ethane
Conference
·
OSTI ID:752894
The authors have studied the spectral shift of the solvated electron in MeOH/C{sub 2}H{sub 6} mixture using pulse radiolysis. The solvated electrons were formed by ionizing the solution. The spectral shift can be explained in terms of MeOH cluster size formed in the solution. With increasing temperature at constant mole fraction of MeOH, the spectral maximum shifts toward low energy. The width at red side increased with increasing temperature, however, there is no significant changes in the blue side of the spectra with temperature.
- Research Organization:
- Argonne National Laboratory, Argonne, IL (US)
- Sponsoring Organization:
- US Department of Energy (US)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 752894
- Report Number(s):
- ANL/CHM/CP-101311; TRN: US0003123
- Resource Relation:
- Conference: 5th International Symposium on Supercritical Fluids, Atlanta, GA (US), 04/08/2000--04/12/2000; Other Information: PBD: 9 Mar 2000
- Country of Publication:
- United States
- Language:
- English
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