Effects of oxygen and catalyst on tetraphenylborate decomposition rate
Abstract
Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.
- Authors:
- Publication Date:
- Research Org.:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Org.:
- US Department of Energy (US)
- OSTI Identifier:
- 750108
- Report Number(s):
- WSRC-TR-99-00279
TRN: US0001345
- DOE Contract Number:
- AC09-96SR18500
- Resource Type:
- Technical Report
- Resource Relation:
- Other Information: PBD: 15 Dec 1999
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; SAVANNAH RIVER PLANT; RADIOACTIVE WASTE PROCESSING; ORGANIC BORON COMPOUNDS; SLURRIES; DECOMPOSITION; OXYGEN; PALLADIUM; CATALYTIC EFFECTS
Citation Formats
Walker, D D. Effects of oxygen and catalyst on tetraphenylborate decomposition rate. United States: N. p., 1999.
Web. doi:10.2172/750108.
Walker, D D. Effects of oxygen and catalyst on tetraphenylborate decomposition rate. United States. https://doi.org/10.2172/750108
Walker, D D. 1999.
"Effects of oxygen and catalyst on tetraphenylborate decomposition rate". United States. https://doi.org/10.2172/750108. https://www.osti.gov/servlets/purl/750108.
@article{osti_750108,
title = {Effects of oxygen and catalyst on tetraphenylborate decomposition rate},
author = {Walker, D D},
abstractNote = {Previous studies indicate that palladium catalyzes rapid decomposition of alkaline tetraphenylborate slurries. Oxygen inhibits the reaction at low temperature (25 C), presumably by preventing activation of the catalyst. The present study investigated oxygen's inhibiting effectiveness at higher temperature (45 C) and catalyst concentrations.},
doi = {10.2172/750108},
url = {https://www.osti.gov/biblio/750108},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Dec 15 00:00:00 EST 1999},
month = {Wed Dec 15 00:00:00 EST 1999}
}
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