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Title: Laboratory investigation of steam adsorption in geothermal reservoir rocks

Technical Report ·
DOI:https://doi.org/10.2172/7038730· OSTI ID:7038730

Some vapor-dominated geothermal reservoirs and low-permeability gas reservoirs exhibit anomalous behavior that may be caused by surface adsorption. For example, geothermal reservoirs in the Larderello are of Italy and reservoirs in the Geysers Geothermal Field, California produce little, if any, liquid. Yet to satisfy material balance constraints, another phase besides steam must be present. If steam adsorption occurring in significant amounts is not accounted for, the reserves will be grossly under-estimated. In addition, well tests may be misinterpreted because the pressure response is delayed owing to be adsorbed material leaving or entering the gaseous phase. In the present research the role of adsorption in geothermal reservoirs in investigated. Two sets of laboratory equipment were constructed to measure adsorption isotherms of cores from Berea sandstone, Larderello, and The Geysers. Seven experimental runs were completed using nitrogen on the low temperature apparatus at -196/sup 0/C. Eight runs were conducted using steam on the high temperature apparatus at temperatures ranging from 150 C to 207/sup 0/C. The largest specific surface area and the greatest nitrogen adsorption isotherm were measured on the Berea sandstone, followed by a core from Larderello and then The Geysers. Difficulties in determining whether a system had reached equilibrium at the end of each step lead to questions regarding the magnitude of adsorption measured by the steam runs. Nevertheless, adsorption was observed and the difficulties themselves were useful indicators of needed future research.

Research Organization:
Stanford Univ., CA (USA). Stanford Geothermal Program
DOE Contract Number:
AS03-80SF11459; AS07-84ID12529
OSTI ID:
7038730
Report Number(s):
SGP-TR-115; ON: DE88012261
Resource Relation:
Other Information: Portions are illegible in microfiche products
Country of Publication:
United States
Language:
English