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Title: Permeability changes in coal resulting from gas desorption

Technical Report ·
DOI:https://doi.org/10.2172/6812549· OSTI ID:6812549

During this quarter, work was continued on measuring the methane sorption capacity of dispersed organic matter in gas shales and maceral concentrates derived from a Kentucky coal. Although previous results have demonstrated that the microbalance technique is successful in generating sorption isotherm curves, the accuracy of the technique has not been well established. The only previous test that allowed a comparison between gravimetric data and volumetric data showed a significant discrepancy with the gravimetric data indicating a considerably greater sorption quantities than the volumetric data. During the present quarter we took advantage of an opportunity to join in a round-robin analysis of sorption capacity of carbonatious shales. A suite of four samples was sent to six laboratories with each lab measuring sorption capacity for methane and reporting the results to a central lab which would compile all of the data for comparitive purposes. Of course, none of the other laboratories were using the gravimetric approach for measuring methane sorption capacity. So this provides a unique opportunity to test the accuracy of our methods.

Research Organization:
Alabama Univ., University, AL (United States). Dept. of Geology
Sponsoring Organization:
USDOE; USDOE, Washington, DC (United States)
DOE Contract Number:
FG22-89PC89764
OSTI ID:
6812549
Report Number(s):
DOE/PC/89764-T12; ON: DE93006433
Country of Publication:
United States
Language:
English