Vacuum uv spectroscopy and photochemistry. V. Spectra, ionization, and molecular interactions. Annual report, September 15, 1966-September 14, 1967
The first part of the report concerns itself with studies on photoionization, ionizing energy transfer and vacuum ultraviolet spectroscopy of olefins. In the second part of the report, semi-empirical methods of calculation have been examined and applied to predict the spectra and ionization potentials of some organo-metallics. The third part of the report contains a basic contribution towards understanding the mechanism of interaction of radiation with matter as well as the interaction between molecules in the condensed phase. The mechanism of the phosphorescence emission is understood and the effects of environmental perturbations is examined. Theoretical and experimental examination of the origin of optical rotation has been carried out and reported.
- Research Organization:
- California Univ., Los Angeles (USA). Dept. of Chemistry
- DOE Contract Number:
- AT03-76ER70091
- OSTI ID:
- 6548326
- Report Number(s):
- DOE/ER/70091-T2
- Country of Publication:
- United States
- Language:
- English
Similar Records
Vacuum Ultraviolet Pulsed Field Ionization-Photoelectron and Infrared-Photoinduced Rydberg Ionization Study of trans-1,3-butadiene
A vacuum ultraviolet laser pulsed field ionization-photoion study of methane (CH4): Determination of the appearance energy of methylium from methane with unprecedented precision and the resulting impact on the bond dissociation energies of CH4 and CH4+
Related Subjects
GENERAL PHYSICS
ALKENES
PHOTOIONIZATION
ULTRAVIOLET SPECTRA
ORGANOMETALLIC COMPOUNDS
IONIZATION POTENTIAL
EXTREME ULTRAVIOLET RADIATION
FARADAY EFFECT
PHOSPHORESCENCE
ELECTROMAGNETIC RADIATION
HYDROCARBONS
IONIZATION
LUMINESCENCE
ORGANIC COMPOUNDS
RADIATIONS
SPECTRA
ULTRAVIOLET RADIATION
640301* - Atomic
Molecular & Chemical Physics- Beams & their Reactions