Analysis of residual organic materials in aqueous radioactive streams from the Purex process
New solid phase extraction methods have been developed to allow determination of residual normal paraffin hydrocarbon (NPH) and tri-n-butyl phosphate (TBP) in aqueous radioactive streams from the Purex process. The techniques concentrate organic materials and separate them from radioactive species for analysis by gas chromatography. TBP and NPH have good radiolytic and chemical stability and have low aqueous solubility. However, they can contaminate aqueous streams and cause processing difficulties. Knowledge of the concentration of organic materials in aqueous waste is useful in assessing impact on pollution control equipment. The storage quality of diluent-washed aqueous plutonium product solution can be determined by a gas chromatographic analysis for residual TBP. 4 refs., 1 fig., 7 tabs.
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
- DOE Contract Number:
- AC09-76SR00001
- OSTI ID:
- 6531172
- Report Number(s):
- DP-1744; ON: DE87010562; TRN: 87-023174
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ALKANES
EXTRACTION
PUREX PROCESS
RADIOACTIVE EFFLUENTS
TBP
AQUEOUS SOLUTIONS
GAS CHROMATOGRAPHY
SAMPLING
BUTYL PHOSPHATES
CHROMATOGRAPHY
DISPERSIONS
ESTERS
HYDROCARBONS
MATERIALS
MIXTURES
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORIC ACID ESTERS
RADIOACTIVE MATERIALS
RADIOACTIVE WASTES
REPROCESSING
SEPARATION PROCESSES
SOLUTIONS
WASTES
050800* - Nuclear Fuels- Spent Fuels Reprocessing