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Title: Experiments and Computational Modeling of Pulverized-Clak Ignition.

Technical Report ·
DOI:https://doi.org/10.2172/643548· OSTI ID:643548

Under typical conditions of pulverized-coal combustion, which is characterized by fine particles heated at very high rates, there is currently a lack of certainty regarding the ignition mechanism of bituminous and lower rank coals. It is unclear whether ignition occurs first at the particle-oxygen interface (heterogeneous ignition) or if it occurs in the gas phase due to ignition of the devolatilization products (homogeneous ignition). Furthermore, there have been no previous studies aimed at determining the dependence of the ignition mechanism on variations in experimental conditions, such as particle size, oxygen concentration, and heating rate. Finally, there is a need to improve current mathematical models of ignition to realistically and accurately depict the particle-to-particle variations that exist within a coal sample. Such a model is needed to extract useful reaction parameters from ignition studies, and to interpret ignition data in a more meaningful way. We propose to examine fundamental aspects of coal ignition through (1) experiments to determine the ignition mechanism of various coals by direct observation, and (2) modeling of the ignition process to derive rate constants and to provide a more insightful interpretation of data from ignition experiments. We propose to use a novel laser-based ignition experiment to achieve our objectives.

Research Organization:
North Carolina Agricultural and Technical State Univ., Greensboro, NC (United States). Dept. of Mechanical Engineering
Sponsoring Organization:
USDOE Assistant Secretary for Fossil Energy, Washington, DC (United States)
DOE Contract Number:
FG22-96PC96221
OSTI ID:
643548
Report Number(s):
DOE/PC/96221-T2; ON: DE98051838
Resource Relation:
Other Information: PBD: 1 Aug 1997
Country of Publication:
United States
Language:
English