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Title: Characterization of the C1 and C2 waste tanks located in the BVEST system at ORNL

Technical Report ·
DOI:https://doi.org/10.2172/631172· OSTI ID:631172

There was a major effort to sample and analyze the Active Liquid Low-Level Waste (LLLW) tanks at ORNL which include the Melton Valley Storage Tanks (MVST) and the Bethel Valley Evaporator Service Tanks (BVEST). The characterization data summarized in this report was needed to address waste processing options, address concerns dealing with the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the waste characteristics with respect to the waste acceptance criteria (WAC) for WIPP and Nevada Test Site (NTS), address criticality concerns, and meet DOT requirements for transporting the waste. This report discusses the analytical characterization data for the supernatant and sludge in the BVEST waste tanks C-1 and C-2. The isotopic data presented in this report supports the position that fissile isotopes of uranium ({sup 233}U and {sup 235}U) and plutonium ({sup 239}Pu and {sup 241}Pu) were denatured as required by the administrative controls stated in the ORNL LLLW waste acceptance criteria (WAC). In general, the sludge in tanks C1 and C2 was found to be hazardous based on RCRA characteristics and the transuranic alpha activity was well above the 100 nCi/g limit for TRU waste. Additional characteristics of the C1 and C2 sludge inventory relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste (RH-TRU) requirements for disposal of the waste in WIPP.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)
DOE Contract Number:
AC05-96OR22464
OSTI ID:
631172
Report Number(s):
ORNL/TM-13546; ON: DE98006008; TRN: 98:007031
Resource Relation:
Other Information: PBD: Feb 1998
Country of Publication:
United States
Language:
English