Thermodynamics of insulated pressure vessels for vehicular hydrogen storage
This paper studies the application of insulated pressure vessels for hydrogen-fueled light-duty vehicles. Insulated pressure vessels can store liquid hydrogen (LH2); low-temperature (90 K) compressed hydrogen (CH2); or ambient temperature CH2. In this analysis, hydrogen temperatures, pressures and venting losses am calculated for insulated pressure vessels fueled with LH2 or with low-temperature CH2, and the results are compared to those obtained in low-pressure LH2 tanks. Hydrogen losses are calculated as a function of daily driving distance during normal operation; as a function of time during long periods of vehicle inactivity; and as a function of initial vessel temperature during fueling. The number of days before any venting losses occur is also calculated as a function of the daily driving distance. The results show that insulated pressure vessels have packaging characteristics comparable to those of conventional, low-pressure LH2 tanks (low weight and volume), with greatly improved dormancy and much lower boil-off. Insulated pressure vessels used in a 17 km/l (40 mpg) car do not lose any hydrogen when the car is driven at least 15 km/day in average. Since almost all cars are driven for longer distances, most cars would never lose any hydrogen. Losses during long periods of parking are also relatively small. Due to their high-pressure capacity, these vessels would retain about a third of their full charge even after a very long dormancy, so that the owner would not risk running out of fuel. If an insulated pressure vessel reaches ambient temperature, it can be cooled down very effectively by fueling it with LH2 with no losses during fueling. The vessel has good thermal performance even when thermally insulated with inexpensive microsphere insulation. In addition, the insulated pressure vessels greatly ease fuel availability and infrastructure requirements, since it would be compatible with both compressed and cryogenic hydrogen reveling.
- Research Organization:
- Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- Sponsoring Organization:
- USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States)
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 629976
- Report Number(s):
- UCRL-JC-128388; CONF-971115-; ON: DE98051280
- Resource Relation:
- Conference: International mechanical engineering congress and exposition, Dallas, TX (United States), 16-21 Nov 1997; Other Information: PBD: Jun 1997
- Country of Publication:
- United States
- Language:
- English
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