Coal liquefaction process solvent characterization and evaluation: Technical progress report, January 1, 1986--March 31, 1986

Technical Report · Tue Jul 01 00:00:00 EDT 1986

DOI:https://doi.org/10.2172/6213673· OSTI ID:6213673

Winschel, R. A.; Robbins, G. A.; Burke, F. P.

Conoco Coal research Division is characterizing samples of direct coal liquefaction process oils based on a variety of analytical techniques to provide a detailed description of the chemical composition of the oils, to more fully understand the interrelationship of process oil composition and process operations, to aid in plant operation, and to lead to process improvements. The approach taken is to obtain analyses of a large number of well-defined process oils taken during periods of known operating conditions and known process performance. A variety of coal liquefaction process oils were dewaxes by variants of commercial processes in order to improve their quality as donor solvents. Twenty-five oils were analyzed from Hydrocarbon Research Incorporated's (HRI) Catalytic Two-Stage Liquefaction (CTSL) Run 227- 27. Ten microautoclave tests were made to ''calibrate'' the reactivity of our standard coal. Nineteen samples of coal and reaction products of coal and potassium/crown ether, supplied by Purdue University, were analyzed by infrared spectroscopy to derive quantitative and qualitative structural information. 22 refs., 13 figs., 38 tabs.

• Research Organization: Conoco, Inc., Library, PA (USA). Coal Research Div.
• DOE Contract Number: AC22-84PC70018
• OSTI ID: 6213673
• Report Number(s): DOE/PC/70018-22; ON: DE89013123
• Resource Relation: Other Information: Portions of this document are illegible in microfiche products
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
02 PETROLEUM
COAL
STRUCTURAL CHEMICAL ANALYSIS
COAL LIQUEFACTION
COAL LIQUIDS
DISTILLATES
PETROLEUM RESIDUES
ADDITIVES
AROMATICS
ASPHALTENES
AUTOCLAVES
CALIBRATION
CATALYSTS
CHEMICAL COMPOSITION
COPROCESSING
DERIVATIZATION
DEWAXING
FRACTIONATION
INFRARED SPECTRA
IRON OXIDES
ORGANIC SOLVENTS
PETROLEUM
PHENOLS
PROGRESS REPORT
TEMPERATURE EFFECTS
WATER
YIELDS
ASPHALTS
BITUMENS
CARBONACEOUS MATERIALS
CHALCOGENIDES
CHEMICAL REACTIONS
DOCUMENT TYPES
ENERGY SOURCES
FLUIDS
FOSSIL FUELS
FUELS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
IRON COMPOUNDS
LIQUEFACTION
LIQUIDS
MATERIALS
ORGANIC COMPOUNDS
OTHER ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PETROLEUM FRACTIONS
PROCESSING
SEPARATION PROCESSES
SOLVENTS
SPECTRA
TAR
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPOUNDS
010405* - Coal
Lignite
& Peat- Hydrogenation & Liquefaction
010600 - Coal
Lignite
& Peat- Properties & Composition
023000 - Petroleum- Properties & Composition