Modifiers in rhodium catalysts for carbon monoxide hydrogenation: Structure-activity relationships
This report is aimed at identifying interesting modified rhodium systems and elucidating structure-activity relationships in these systems with the overall goal of understanding the scientific issues in the catalytic conversion of syngas to oxygenates. Specific additives (sodium and molybdenum) are selected based on the scoping experiments. The effect of the additives on supported rhodium catalysts is then investigated. Throughout the investigation, experiments and analysis were performed on real systems instead of ideal systems. 374 refs., 82 figs., 57 tabs.
- Research Organization:
- Delaware Univ., Newark (USA). Dept. of Chemical Engineering
- DOE Contract Number:
- FG22-84PC70780
- OSTI ID:
- 6119986
- Report Number(s):
- DOE/PC/70780-T10; ON: DE89013802
- Resource Relation:
- Other Information: Thesis (Ph.D.). Portions of this document are illegible in microfiche products
- Country of Publication:
- United States
- Language:
- English
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Modifiers in rhodium catalysts for carbon monoxide hydrogenation: Structure-activity relationships
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Miscellaneous
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Sun Jan 01 00:00:00 EST 1989
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OSTI ID:6119986
Trifunctional catalysts for conversion of syngas to alcohols: Tenth quarterly report for period December 1, 1986 to February 28, 1987. [CO chemisorbed on rhodium/alumina catalysts - one series modified by molybdena and the other by sodium addition]
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Wed Mar 25 00:00:00 EST 1987
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OSTI ID:6119986
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