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Title: Identification of weak autoionizing resonances observed through fluorescence from the satellite states of Ar{sup +}

Technical Report ·
DOI:https://doi.org/10.2172/603606· OSTI ID:603606
; ;  [1]
  1. Univ. of Nebraska, Lincoln, NE (United States); and others

Photoionization accompanied by excitation of the residual ionic state violates an independent electron model since, according to QED, photons interact only with individual electrons. By allowing measurements at a threshold event with high resolution, the observation of the fluorescence from the decay of these excited states (satellite states) is a sensitive method in the study of electron-electron interactions, providing complementary information to photoelectron spectroscopy. In the measurements reported here, an atomic beam of argon has been photoionized with 34 to 39 eV synchrotron radiation at beamline 9.0.1 of the Advanced Light Source. This energy range encompasses the 3p{sup 4} [{sup 3}P] 4p {sup 4}P, {sup 2}P, and {sup 2}D as well as the [{sup 1}D]4p {sup 2}F satellite states of Ar{sup +}. By observing the fine-structure resolved fluorescence from these satellite states, new Rydberg series and extensions of previously known series have been resolved with an energy resolution of 3 meV. With the high photon flux available from the high resolution monochromator of beamline 9.0.1, even the weakly excited [{sup 3}P] 4p ({sup 2}S) ns,d autoionizing structure has been observed for the first time.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
OSTI ID:
603606
Report Number(s):
LBNL-39981; ON: DE97007345; CNN: Grant PHY-9419505; TRN: 98:009573
Resource Relation:
Other Information: PBD: Apr 1997; Related Information: Is Part Of Advanced light source: Compendium of user abstracts 1993--1996; PB: 622 p.
Country of Publication:
United States
Language:
English