skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Interactions of structurally modified surfactants with reservoir minerals: Calorimetric, spectroscopic and electrokinetic study

Technical Report ·
DOI:https://doi.org/10.2172/5967258· OSTI ID:5967258

The objective of this project is to elucidate mechanisms of adsorption of structurally modified surfactants on reservoir minerals and to develop a full understanding of the effect of the surfactant structure on the nature of the adsorbed layers at the molecular level. An additional aim is to study the adsorption of surfactant mixtures on simple well-characterized minerals and on complex minerals representing real conditions. The practical goal of these studies is the identification of the optimum surfactant structures and their combinations for micellar flooding. In this work, the experiments on adsorption were focussed on the position of sulfonate and methyl groups on the aromatic ring of alkyl xylene sulfonates. A multi-pronged approach consisting of calorimetry, electrokinetics, wettability and spectroscopy is planned to elucidate the adsorption mechanism of surfactants and their mixtures on minerals such as alumina and kaolinite. 32 refs., 15 figs., 7 tabs.

Research Organization:
Columbia Univ., New York, NY (USA). School of Engineering and Applied Science
Sponsoring Organization:
USDOE; USDOE, Washington, DC (USA)
DOE Contract Number:
FG22-89BC14432
OSTI ID:
5967258
Report Number(s):
DOE/BC/14432-5; ON: DE91002228
Country of Publication:
United States
Language:
English