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Title: Thermal stabilization of uranium mill tailings

Conference ·
DOI:https://doi.org/10.1021/es00127a006· OSTI ID:5914663

The sintering of tailings at high temperatures (1200/sup 0/C) has shown promise as a conditioning approach that greatly reduces the /sup 222/Rn emanation of uranium mill tailings. The structure of thermally stabilized tailings has been appreciably altered producing a material that will have minimal management requirements and will be applicable to on-site processing and disposal. The mineralogy of untreated tailings is presented to define the structure of the original materials. Quartz predominates in most tailings samples; however, appreciable quantities of gypsum, clay, illite, or albites are found in some tailings. Samples from the Durango and Shiprock sites have plagioclase-type aluminosilicates and non-aluminum silicates as major components. The iron-rich vanadium tailings from the Salt Lake City site contain appreciable quantities of ..cap alpha..-hematite and chloroapatite. The reduction in radon emanation power and changes in mineralogy as a function of sintering temperature (500 to 1200(NiAsS) are considered possible species for consideraed. The calculated activity data of the various carbonate, sulfate and hydroxide species in the Li/sup +/Na/sup +/K/sup +//CO/sub 3/ = SO/sub 4/ = OH/sup -/ system have been combined f liquidus surfaces, and estimated error limits are given for each system. A comng payback period, but as the initial cost of the SAHPS is reduced and fuel prices increase, the payback period of a SAHPS will be shorter and could be competitive with other conventional heating/cooling systems.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
5914663
Report Number(s):
LA-UR-81-2734; CONF-811049-1; ON: DE82000562; TRN: 82-000236
Resource Relation:
Journal Volume: 18; Journal Issue: 9; Conference: 4. symposium on uranium mill tailings management, Fort Collins, CO, USA, 26 Oct 1981
Country of Publication:
United States
Language:
English