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Title: Vibrational spectroscopy of shock-compressed liquid CO

Conference ·

Single-pulse, multiplex, coherent anti-Stokes Raman spectroscopy (CARS) was used to observe the vibrational spectra of liquid CO shock compressed to several pressures and temperatures up to 9.9 GPa and 2010 K. The experimental spectra were compared to synthetic spectra calculated using a semiclassical model for CARS intensities and estimated vibrational frequencies, peak Raman susceptibilities and Raman line widths. A comparison of these data with result in the isoelectronic and materially very similar N{sub 2} show a significant difference in vibrational frequency shift with pressure. 21 refs., 2 figs.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE; USDOE, Washington, DC (USA)
DOE Contract Number:
W-7405-ENG-36
OSTI ID:
5728988
Report Number(s):
LA-UR-91-1666; CONF-9107105-9; ON: DE91013204
Resource Relation:
Conference: 1991 American Physical Society (APS) conference on shock compression of condensed matter, Williamsburg, VA (USA), 17-20 Jul 1991
Country of Publication:
United States
Language:
English