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Title: Pyrite thermochemistry, ash agglomeration, and char fragmentation during pulverized coal combustion

Technical Report ·
DOI:https://doi.org/10.2172/5683888· OSTI ID:5683888

The objective of the present work is to introduce an experimental program that will eventually lead to time-resolved iron ash composition over the technological operating domain. The preceding literature survey suggests two important stipulations on any such experimental program. The first stipulation is that good control must be established over the operating conditions, to accurately quantify their effects. The other is that data must be obtained rapidly, to thoroughly cover the important operating domain. This work presents a series of studies that has characterized the desulfurization of pyrite during the early stages of combustion. An experimental system was established and used to monitor the effects of oxygen, temperature, and residence time on the evolution of condensed phase products of the combustion of pure pyrite. (VC)

Research Organization:
Stanford Univ., CA (United States). High Temperature Gasdynamics Lab.
Sponsoring Organization:
USDOE; USDOE, Washington, DC (United States)
DOE Contract Number:
FG22-87PC79909
OSTI ID:
5683888
Report Number(s):
DOE/PC/79909-T3; ON: DE92004845
Country of Publication:
United States
Language:
English