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Title: High temperature and high resolution uv photoelectron spectroscopy using supersonic molecular beams

Conference ·
OSTI ID:5641917

A high temperature molecular beam source with electron bombardment heating has been built for high resolution photoelectron spectroscopic studies of high temperature species and clusters. This source has the advantages of: producing an intense, continuous, seeded molecular beam, eliminating the interference of the heating mechanism from the photoelectron measurement. Coupling the source with our hemispherical electron energy analyzer, we can obtain very high resolution HeI{alpha} (584{angstrom}) photoelectron spectra of high temperature species. Vibrationally-resolved photoelectron spectra of PbSe, As{sub 2}, As{sub 4}, and ZnCl{sub 2} are shown to demonstrate the performance of the new source. 25 refs., 8 figs., 1 tab.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
DOE/ER
DOE Contract Number:
AC03-76SF00098
OSTI ID:
5641917
Report Number(s):
LBL-27583; CONF-890738-2; ON: DE90000176; TRN: 89-024348
Resource Relation:
Conference: 4. international conference on electron spectroscopy, Honolulu, HI (USA), 10-14 Jul 1989
Country of Publication:
United States
Language:
English