Tritium isotope separation from light and heavy water by bipolar electrolysis

Conference · Tue Jan 01 00:00:00 EST 1980

OSTI ID:5378667

Petek, M; Ramey, D W; Taylor, R D; Kobisk, E H

A process for separating tritium from light and heavy water is described. Hydrogen is transferred at and through bipolar electrodes at rates H > D > T. In a cell containing several bipolar electrodes placed in series between two terminal electrodes, a flow of hydrogen is established from the terminal anode compartment toward the terminal cathode. An electrolyte feed containing tritium is continuously added to the system and is subsequently transported countercurrent to the hydrogen mass transfer. A cascaded system is established, in which effluent streams enriched and depleted in tritium can be withdrawn. The voltage drop is smaller at any bipolar electrode as compared to the voltage for normal electrolysis. Cell design is compact because isotope separation occurs at bipolar electrodes without evolution of gas. Isotope separation was demonstrated in laboratory cells where a steady-state tritium concentration gradient was attained. This gradient was in agreement with concentrations calculated from a derived mathematical model.

• Research Organization: Oak Ridge National Lab., TN (USA)
• DOE Contract Number: W-7405-ENG-26
• OSTI ID: 5378667
• Report Number(s): CONF-800427-15; TRN: 80-011416
• Resource Relation: Conference: Tritium technology in fission, fusion, and isotopic applications, Dayton, OH, USA, 29 Apr 1980
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
HEAVY WATER
SEPARATION PROCESSES
TRITIUM
WATER
ELECTROLYSIS
MATHEMATICAL MODELS
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
LIGHT NUCLEI
LYSIS
NUCLEI
ODD-EVEN NUCLEI
OXYGEN COMPOUNDS
RADIOISOTOPES
YEARS LIVING RADIOISOTOPES
400203* - Isotope Exchange & Isotope Separation- (-1987)