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Title: Preparation and some properties of Cu-Li alloys containing up to 20 at. % Li

Abstract

Lithium strongly segregates to the surface of Cu-Li alloys, thus substantially lowering the Cu sputtering yield relative to pure Cu. Use of Cu-Li limiters or divertors in tokamaks can therefore be expected to be beneficial in limiting high-Z plasma impurity influx. A large scale (100-200g) method for the preparation of Cu-Li alloys is described. Analysis reveals that on solidification from the melt stratification occurs which leads to compositional inhomogeneity. The results are discussed in the light of the Cu-Li binary phase diagram and rationalized on the basis of large density differences between Cu and Cu-Li solid solutions. It is concluded that obtaining homogeneous Cu-Li solid solutions is a nontrivial task.

Authors:
; ;
Publication Date:
Research Org.:
Argonne National Lab., IL (USA)
OSTI Identifier:
5108902
Report Number(s):
CONF-8510160-4
ON: DE86001786
DOE Contract Number:  
W-31-109-ENG-38
Resource Type:
Conference
Resource Relation:
Conference: ASM metals congress - international conference on surface modifications, Toronto, Ontario, Canada, 13 Oct 1985; Other Information: Portions of this document are illegible in microfiche products
Country of Publication:
United States
Language:
English
Subject:
70 PLASMA PHYSICS AND FUSION TECHNOLOGY; 36 MATERIALS SCIENCE; COPPER ALLOYS; CHEMICAL PREPARATION; PHASE DIAGRAMS; DIVERTORS; MATERIALS TESTING; LIMITERS; LITHIUM ALLOYS; PHYSICAL PROPERTIES; SPUTTERING; TOKAMAK DEVICES; ALLOYS; CLOSED PLASMA DEVICES; DIAGRAMS; SYNTHESIS; TESTING; THERMONUCLEAR DEVICES; 700209* - Fusion Power Plant Technology- Component Development & Materials Testing; 360101 - Metals & Alloys- Preparation & Fabrication

Citation Formats

Mendelsohn, M, Krauss, A R, and Gruen, D M. Preparation and some properties of Cu-Li alloys containing up to 20 at. % Li. United States: N. p., 1985. Web.
Mendelsohn, M, Krauss, A R, & Gruen, D M. Preparation and some properties of Cu-Li alloys containing up to 20 at. % Li. United States.
Mendelsohn, M, Krauss, A R, and Gruen, D M. 1985. "Preparation and some properties of Cu-Li alloys containing up to 20 at. % Li". United States. https://www.osti.gov/servlets/purl/5108902.
@article{osti_5108902,
title = {Preparation and some properties of Cu-Li alloys containing up to 20 at. % Li},
author = {Mendelsohn, M and Krauss, A R and Gruen, D M},
abstractNote = {Lithium strongly segregates to the surface of Cu-Li alloys, thus substantially lowering the Cu sputtering yield relative to pure Cu. Use of Cu-Li limiters or divertors in tokamaks can therefore be expected to be beneficial in limiting high-Z plasma impurity influx. A large scale (100-200g) method for the preparation of Cu-Li alloys is described. Analysis reveals that on solidification from the melt stratification occurs which leads to compositional inhomogeneity. The results are discussed in the light of the Cu-Li binary phase diagram and rationalized on the basis of large density differences between Cu and Cu-Li solid solutions. It is concluded that obtaining homogeneous Cu-Li solid solutions is a nontrivial task.},
doi = {},
url = {https://www.osti.gov/biblio/5108902}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1985},
month = {Tue Jan 01 00:00:00 EST 1985}
}

Conference:
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