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Title: Novel selective surface flow (SSF{sup TM}) membranes for the recovery of hydrogren from waste gas streams. Final report

Technical Report ·
DOI:https://doi.org/10.2172/477622· OSTI ID:477622
 [1]
  1. USDOE, Washington, DC (United States)

The waste streams are off-gas streams from various chemical/refinery operations. In Phase I, the architecture of the membrane and the separation device were defined and demonstrated. The system consists of a shell-and-tube separator in which the gas to be separated is fed to the tube side, the product is collected as high pressure effluent and the permeate constitutes the waste/fuel stream. Each tube, which has the membrane coated on the interior, does the separation. A multi- tube separator device containing 1 ft{sup 2} membrane area was built and tested. The engineering data were used for designing a process for hydrogen recovery from a fluid catalytic cracker off-gas stream. First-pass economics showed that overall cost for hydrogen production is reduced by 35% vs on-purpose production of hydrogen by steam- methane reforming. The hydrogen recovery process using the SSF membrane results in at least 15% energy reduction and significant decrease in CO{sub 2} and NO{sub x} emissions.

Research Organization:
Department of Energy, Albuquerque, NM (United States). Albuquerque Operations Office; US Department of Energy (USDOE), Washington DC (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States)
DOE Contract Number:
FC04-93AL94461
OSTI ID:
477622
Report Number(s):
DOE/AL/94461-1; ON: DE97000783
Resource Relation:
Other Information: PBD: Aug 1995
Country of Publication:
United States
Language:
English