Study on durability for thermal cycle of planar SOFC
- Tonen Corp., Saitama (Japan); and others
TONEN CORPORATION has developed planar type SOFC since 1986. We demonstrated the output of 1.3 kW in 1991 and 5.1 kW in 1995. Simultaneously we have studied how to raise electric efficiency and reliability utilizing hydrogen and propane as fuel. Durability for thermal cycle is one of the most important problems of planar SOFC to make it more practical. The planar type SOFC is made up of separator, zirconia electrolyte and glass sealant. The thermal expansion of these components are expected to be the same value, however, they still possess small differences. In this situation, a thermal cycle causes a thermal stress due to the difference of the cell components and is often followed by a rupture in cell components, therefore, the analysis of the thermal stress should give us much useful information. The thermal cycle process consists of a heating up and cooling down procedure. Zirconia electrolyte is not bonded to the separator under the condition of the initial heating up procedure, and glass sealant becomes soft or melts and glass seals spaces between the zirconia and separator. The glass sealant becomes harder with the cooling down procedure. Moreover, zirconia is tightly bonded with separator below a temperature which is defined as a constraint temperature and thermal stress also occurs. This indicates that the heating up process relaxes the thermal stress and the cooling down increases it. In this paper, we simulated dependence of the stress on the sealing configuration, thermal expansion of sealant and constraint temperature of sealant glass. Furthermore, we presented SOFC electrical properties after a thermal cycle.
- Research Organization:
- Fuel Cell Seminar Organizing Committee (United States)
- OSTI ID:
- 460185
- Report Number(s):
- CONF-961107-Absts.; ON: TI97001494; TRN: 97:001723-0037
- Resource Relation:
- Conference: Fuel cell seminar, Kissimmee, FL (United States), 17-20 Nov 1996; Other Information: PBD: [1996]; Related Information: Is Part Of Fuel cells seminar; PB: 794 p.
- Country of Publication:
- United States
- Language:
- English
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