Effect of lead content on phase evolution and microstructural development in Ag-clad Bi-2223 composite conductors
- Argonne National Lab., IL (United States). Chemical Technology Div.
A two powder process was used to prepare silver-sheathed monofilamentary Bi{sub 1.8}Pb{sub x}Sr{sub 1.98}Ca{sub 1.97}Cu{sub 3.08}O{sub y} (Bi-2223) tapes with varying lead contents, x, from 0.2 to 0.5. The resulting tapes were subjected to thermomechanical processing and then characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive x-ray analysis (EDX). Layered phase texture was accessed using image analysis software on scanned SEM micrographs. Transport currents were measured at 77 K and zero field by the four-probe method. It was found that tapes with low lead content (X = 0.2 and 0.25) showed incomplete conversion to Bi-2223, had small grain size and poor c-axis texture. Tapes having higher lead content (x = 0.4 and 0.5) also showed incomplete conversion and the presence of lead-rich secondary phases. Tapes with lead content x = 0.3 and 0.35 showed complete conversion to Bi-2223, and had the least amount of secondary phases, the best c-axis texture, and the highest transport current (j{sub c}). The carbon content of the precursor powder also had a strong influence on secondary-phase chemistry.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 446397
- Report Number(s):
- ANL/CMT/CP-90759; CONF-970201-18; ON: DE97003236; TRN: 97:006521
- Resource Relation:
- Conference: 126. annual meeting of the Minerals, Metals and Materials Society, Orlando, FL (United States), 9-13 Feb 1997; Other Information: PBD: Feb 1997
- Country of Publication:
- United States
- Language:
- English
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