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Title: Raman probe. Innovative technology summary report

Technical Report ·
DOI:https://doi.org/10.2172/354880· OSTI ID:354880

The Raman probe is deployed in high-level waste tanks with the cone penetrometer (CPT). These technologies are engineered and optimized to work together. All of the hardware is radiation hardened, designed for and tested in the high-radiation, highly caustic chemical environment of US Department of Energy`s (DOE`s) waste storage tanks. When deployed in tanks, the system is useful for rapidly assessing the species and concentrations of organic-bearing tank wastes. The CPT was originally developed for geological and groundwater applications, with sensors that measure physical parameters such as soil moisture, temperature, and pH. When deployed, it is hydraulically forced directly into the ground rather than using boring techniques utilized by rotary drilling systems. There is a separate Innovative Technology Summary Report for the CPT, so this report will focus on the changes made specifically to support the Raman probe. The most significant changes involve adapting the Raman probe for in-tank and subsurface field use and developing meaningful real-time data analysis. Testing of the complete LLNL system was conducted in a hot cell in the 222-S Laboratory at the Hanford site in summer 1997. Both instruments were tested in situ on solvent-contaminated soils (TCE and PCE) at the Savannah River Site in February and June 1998. This report describes the technology, its performance, its uses, cost, regulatory and policy issues, and lessons learned.

Research Organization:
Dept. of Energy, Office of Science and Technology, Washington, DC (United States)
Sponsoring Organization:
USDOE Office of Environmental Restoration and Waste Management, Washington, DC (United States)
OSTI ID:
354880
Report Number(s):
DOE/EM-0442; ON: DE99002912; IN: OST Reference No. 1544; NC: NONE; TRN: AHC29924%%84
Resource Relation:
Other Information: PBD: Jul 1999
Country of Publication:
United States
Language:
English

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