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Title: Limiting phase separation in epitaxial GaInAsSb

Technical Report ·
DOI:https://doi.org/10.2172/314152· OSTI ID:314152
; ; ;  [1];  [2]
  1. Massachusetts Inst. of Tech., Lexington, MA (United States). Lincoln Lab.
  2. Lockheed Martin Corp., Schenectady, NY (United States)

GaInAsSb alloys are of great interest for lattice-matched thermophotovoltaic (TPV) devices because of the high performance attainable at 2.2 {micro}m. Extension of the TPV device cutoff wavelength to beyond 2.2 {micro}m is especially desirable since the emissive power of the source is significant at these longer wavelengths. However, the GaInAsSb quaternary alloy system exhibits a miscibility gap in the wavelength range of interest, and no devices with cutoff wavelengths longer than 2.3 {micro}m have been demonstrated. This paper reports the successful growth of GaInAsSb alloys which exhibit room temperature photoluminescence (PL) at wavelengths as long as 2.5 {micro}m. TPV devices with cutoff wavelengths out to 2.5 {micro}m exhibit external quantum efficiencies of 57%. These values are comparable to those measured for 2.2 {micro}m devices.

Research Organization:
Knolls Atomic Power Lab. (KAPL), Niskayuna, NY (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Nuclear Energy, Washington, DC (United States)
DOE Contract Number:
AC12-76SN00052
OSTI ID:
314152
Report Number(s):
KAPL-P-000133; K-98189; CONF-981104-; ON: DE99001733; TRN: AHC29907%%69
Resource Relation:
Conference: Fall meeting of the Materials Research Society, Boston, MA (United States), 30 Nov - 4 Dec 1998; Other Information: PBD: Nov 1998
Country of Publication:
United States
Language:
English