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Title: Effect of sulfur on the ductility of copper shaped-charge jets

Conference ·
OSTI ID:288430
; ; ;  [1];  [2]
  1. Lawrence Livermore National Lab., CA (United States)
  2. Army Armament Research, Development and Engineering Center, Dover, NJ (United States)

We have observed that a change in bulk sulfur (S) content imposed by doping has a marked effect on ductility of copper shaped-charge jets as measured by breakup times and length-to-diameter ratios of the particulated jet. Baseline material was Oxygen-Free-Electronic (ofe) copper with a S concentration of 3-4 ppM. Several liners were doped using a Cu sulfide powder pack method to increase the S level up to 9 ppM, while keeping other impurities and microstructure unchanged. Using flash x-ray radiographs to record the formation of jets, both the length-to-diameter ratios of the jet particles and breakup times were measured. Increasing the bulk S content of ofe Cu to 9 ppM, the breakup times decreased from 186 to 147 {mu}s, while the length-to- diameter ratios observed at 260 {mu}s decreased from 8:1 to 5:1. Since the solubility of S in Cu at the processing temperatures is extremely low, we conclude that the bulk rise in S content is due to S segregating to the grain boundaries. Thus, the decrease in ductility of liners doped with S appears directly related to the S content at the grain boundaries.

Research Organization:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States); Department of Defense, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
288430
Report Number(s):
UCRL-JC-123068; CONF-960982-4; ON: DE96013876
Resource Relation:
Conference: 16. international symposium on ballistics, San Francisco, CA (United States), 23-28 Sep 1996; Other Information: PBD: Jul 1996
Country of Publication:
United States
Language:
English