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Title: Molecular hydrodynamics of high explosives

Technical Report ·
DOI:https://doi.org/10.2172/226230· OSTI ID:226230

High explosives release mechanical energy through chemical reactions. Applications of high explosives are vast in the mining and military industries and are beginning to see more civilian applications such as the deployment of airbags in modern automobiles. One of the central issues surrounding explosive materials is decreasing their sensitivity, necessary for their safe handling, while maintaining a high yield. Many practical tests have been devised to determine the sensitivity of explosive materials to shock, to impact, to spark, and to friction. These tests have great value in determining yield and setting precautions for safe handling but tell little of the mechanisms of initiation. How is the mechanical energy of impact or friction transformed into the chemical excitation that initiates explosion? The answer is intimately related to the structure of the explosive material, the size and distribution of grains, the size and presence of open areas such as voids and gas bubbles, and inevitably the bonding between explosive molecules.

Research Organization:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
226230
Report Number(s):
UCRL-ID-119094; ON: TI96009737
Resource Relation:
Other Information: PBD: Nov 1994
Country of Publication:
United States
Language:
English