Role of the resid solvent in catalytic coprocessing with finely divided catalysts. Final report

Technical Report · Mon Jan 01 00:00:00 EST 1996

DOI:https://doi.org/10.2172/219216· OSTI ID:219216

Curtis, C W

The role of the resid in coprocessing coal with petroleum resid has been investigated using model systems. The primary question being investigated is whether resid is participating in reactions with coal or if the resid is acting simply as a diluent. Since hydrogen transfer is an important mechanism by which solvent interacts with coal, hydrogen transfer between naphthenes, saturated alicyclic molecules, that represent resid and aromatic molecules that represent coal were examined in reactions with a high pressure H{sub 2} atmosphere that is typical of actual coprocessing. The model naphthene, perhydropyrene, was chosen as the donor species and the models, anthracene, phenanthrene, and benzophenone, were chosen as the acceptor species. Coprocessing reactions of coal with petroleum resid were performed to evaluate the effect of the chemistry of both constituents on coal conversion and the upgrading of the heavy resid. Three heavy resids, Maya, FHC-623 and Manji were used as the whole resid and as fractions that has been separates into hexane solubles and saturate fractions.

• Research Organization: Auburn Univ., AL (United States). Dept. of Chemical Engineering
• Sponsoring Organization: USDOE, Washington, DC (United States)
• DOE Contract Number: AC22-91PC91055
• OSTI ID: 219216
• Report Number(s): DOE/PC/91055-T13; ON: DE96009825
• Resource Relation: Other Information: PBD: Jan 1996
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
02 PETROLEUM
40 CHEMISTRY
COAL
COPROCESSING
CATALYSTS
PETROLEUM RESIDUES
HYDROAROMATICS
HYDROGEN TRANSFER
BENZOPHENONE
HYDROGENATION
CHEMICAL REACTION KINETICS
MOLYBDENUM COMPOUNDS
CATALYTIC EFFECTS
CONDENSED AROMATICS
ANTHRACENE
PHENANTHRENE
SOLVENTS
EXPERIMENTAL DATA
PROGRESS REPORT