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Title: Experimental measurements of the Hugoniot of stishovite

Technical Report ·
DOI:https://doi.org/10.2172/161450· OSTI ID:161450
 [1];  [2]
  1. Sandia National Labs., Albuquerque, NM (United States). Experimental Impact Physics Dept.
  2. Okayama Univ. (Japan). Inst. for Study of the Earth`s Interior

The crust and mantle of the Earth are primarily composed of silicates. The properties of these materials under compression are of interest for deducing deep-earth composition. As well, the properties of these materials under shock compression are of interest for calculating groundshock propagation. The authors have synthesized, characterized, and performed Hugoniot measurements on monolithic polycrystalline SiO{sub 2} samples which were predominantly stishovite (a high-pressure polymorph). Synthesis was accomplished in a multianvil press with pyrophyllite gaskets and carbon heaters. The samples had densities ranging from 3.80 to 4.07, corresponding to stishovite volume fractions of 0.7 to 0.87, a range confirmed by NMR analysis. Electron microprobe and X-ray fluorescence characterizations showed minor carbon contamination (< 1%), with no other significant impurities. Samples {approximately} 1 mm thick and 3 mm diameter were tested in reverse and forward-ballistics modes on a two-stage light gas gun, using velocity interferometry diagnostics. Impact velocities ranged from 4.0 to 6.5 km/sec. Hugoniot stresses for four tests ranged from 65 to 225 GPa. At higher stresses significant uncertainties arise due to impact tilt/nonplanarity issues. Results are consistent with earlier predictions of the stishovite Hugoniot based on quartz-centered Hugoniot data, static-compression (diamond-anvil cell) data and hydrostatic multianvil cell data. Release behavior appears to be frozen. These results are remarkable in view of the small size of the samples used. Results are compared with current EOS models.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
161450
Report Number(s):
SAND-95-2342; ON: DE96002375; TRN: AHC29601%%4
Resource Relation:
Other Information: PBD: Oct 1995
Country of Publication:
United States
Language:
English