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Title: Kinetic measurement and prediction of the hydrogen outgassing from the polycrystalline LiH/LiOH system

Conference ·

In this report, we present the use of temperature programmed reaction/decomposition (TPR) in the isoconversion mode to measure outgassing kinetics and to make kinetic prediction concerning hydrogen release from the polycrystalline LiH/LiOH system in the absence of any external H{sub 2}O source.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
US Department of Energy (US)
DOE Contract Number:
W-7405-ENG-48
OSTI ID:
15015944
Report Number(s):
UCRL-PROC-210786; TRN: US200509%%457
Resource Relation:
Journal Volume: 347; Journal Issue: 1-2; Conference: Presented at: 26th Compatibility, Aging, and Stockpile Stewardship, Aiken, SC (US), 04/26/2005--04/28/2005; Other Information: PBD: 9 Mar 2005
Country of Publication:
United States
Language:
English

References (11)

Kinetics of the reaction of water vapour with crystalline lithium hydride journal January 1966
The reaction kinetics of lithium salt with water vapor journal June 2002
Ion‐backscattering study of LiOH‐to‐Li 2 O conversion on a LiH substrate journal October 1974
The effects of moisture on LiD single crystals studied by temperature-programmed decomposition journal June 2001
The nature and effects of the thermal stability of lithium hydroxide journal May 2003
Equilibrium pressures of H2O(g) over the Li2O(s)-LiOH(s) system journal December 1993
Die bestimmung kinetischer parameter endothermer zersetzungsreaktionen unter nicht-isothermen bedingungen journal December 1975
Kinetics of dissociation of hydrated cerium(III) sulfate, nitrate and oxalate in air journal November 1985
Isoconversion method for kinetic analysis of solid-state reactions from dynamic thermoanalytical data journal January 1999
Kinetics in Solids journal October 1997
Composition of corrosion films on lithium hydride surfaces after exposure to air report March 1974

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