Spectroscopic and dynamical studies of highly energized small polyatomic molecules

Conference · Wed Dec 01 00:00:00 EST 1993

OSTI ID:139873

Field, R W; Silbey, R J ^[1]

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1. Massachusetts Institute of Technology, Cambridge (United States)

The authors have initiated a program to perform spectroscopic and dynamic studies of small molecules. Large amplitude motions in excited acetylene were discussed along with plans to record the dispersed fluorescence (DF) and the stimulated emission pumping (SEP) spectra. SEP spectra were reported for the formyl radical. A Fourier transform spectrometer was discussed with respect to its ability to probe the structure of radicals. This instrument is capable of performing studies using various techniques such as magnetic rotation spectroscopy and sub-Doppler sideband-OODR Zeman (SOODRZ) spectroscopy.

• Research Organization: Brookhaven National Lab. (BNL), Upton, NY (United States)
• DOE Contract Number: FG02-87ER13671
• OSTI ID: 139873
• Report Number(s): BNL-48923; CONF-9306172-; ON: DE93015758; TRN: 93:002191-0027
• Resource Relation: Conference: 15. combustion research contractors` meeting, Lake Harmony, PA (United States), 2-4 Jun 1993; Other Information: PBD: 1993; Related Information: Is Part Of Fifteenth combustion research conference; PB: 391 p.
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
RADICALS
SPECTROSCOPY
ACETYLENE
FORMYL RADICALS
COMBUSTION
FLUORESCENCE SPECTROSCOPY
STIMULATED EMISSION
ISOMERIZATION
MATHEMATICAL MODELS
EXCITED STATES