skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enhanced bulk heterojunction devices prepared by thermal and solvent vapor annealing processes

Patent ·
OSTI ID:1393176

A method of preparing a bulk heterojunction organic photovoltaic cell through combinations of thermal and solvent vapor annealing are described. Bulk heterojunction films may prepared by known methods such as spin coating, and then exposed to one or more vaporized solvents and thermally annealed in an effort to enhance the crystalline nature of the photoactive materials.

Research Organization:
Univ. of Southern California, Los Angeles, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG36-08GO18022
Assignee:
University of Southern California
Patent Number(s):
9,768,402
Application Number:
13/080,759
OSTI ID:
1393176
Resource Relation:
Patent File Date: 2011 Apr 06
Country of Publication:
United States
Language:
English

References (19)

Solvent annealing process for forming a thin semiconductor film with advantageous properties patent November 2001
Organic devices having a fiber structure patent March 2007
Method for treating a photovoltaic active layer and organic photovoltaic element patent December 2007
Device and method for organic vapor jet deposition patent May 2010
Solvent vapor annealing of organic films patent November 2010
Photovoltaic devices with conductive barrier layers and foil substrates patent June 2012
Derivatized fullerene-based dopants for organic semiconductors patent April 2013
Semiconducting polymers patent May 2013
Solar cell with conductive material embedded substrate patent May 2013
Increased open-circuit-voltage organic photosensitive devices patent-application December 2007
Impact of Solvent Vapor Annealing on the Morphology and Photophysics of Molecular Semiconductor Thin Films journal June 1998
“Solvent Annealing” Effect in Polymer Solar Cells Based on Poly(3-hexylthiophene) and Methanofullerenes journal July 2007
Organic Photovoltaic Cells Based On Solvent-Annealed, Textured Titanyl Phthalocyanine/C60 Heterojunctions journal June 2009
Efficient Squaraine-Based Solution Processable Bulk-Heterojunction Solar Cells journal December 2008
Efficient Solution-Processed Photovoltaic Cells Based on an Anthradithiophene/Fullerene Blend
  • Lloyd, Matthew T.; Mayer, Alex C.; Subramanian, Sankar
  • Journal of the American Chemical Society, Vol. 129, Issue 29, p. 9144-9149 https://doi.org/10.1021/ja072147x
journal July 2007
The Role of Mesoscopic PCBM Crystallites in Solvent Vapor Annealed Copolymer Solar Cells journal February 2009
Temperature-Enhanced Solvent Vapor Annealing of a C3 Symmetric Hexa- peri -Hexabenzocoronene: Controlling the Self-Assembly from Nano- to Macroscale journal January 2009
Efficient, Ordered Bulk Heterojunction Nanocrystalline Solar Cells by Annealing of Ultrathin Squaraine Thin Films journal September 2010
Solution-Processed Squaraine Bulk Heterojunction Photovoltaic Cells journal March 2010