Flexible macrocycles as versatile supports for catalytically active metal clusters

Ryan, Jason D.; Gagnon, Kevin J.; Teat, Simon J.; McIntosh, Ruaraidh D.

doi:10.1039/c6cc00478d

Title: Flexible macrocycles as versatile supports for catalytically active metal clusters

Journal Article · Fri Feb 12 00:00:00 EST 2016 · ChemComm

DOI:https://doi.org/10.1039/c6cc00478d· OSTI ID:1378949

Ryan, Jason D. ^[1]; Gagnon, Kevin J. ^[2]; Teat, Simon J. ^[2]; McIntosh, Ruaraidh D. ^[1]

Heriot-Watt Univ., Riccarton (United Kingdom). Inst. of Chemical Sciences
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Here we present three structurally diverse clusters stabilised by the same macrocyclic polyphenol; t-butylcalix[8]arene. This work demonstrates the range of conformations the flexible ligand is capable of adopting, highlighting its versatility in metal coordination. In addition, a Ti complex displays activity for the ring-opening polymerisation of lactide

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1378949

Journal Information:: ChemComm, Vol. 52, Issue 58; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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A monomeric bowl-like pyrogallol[4]arene Ti ₁₂ coordination complex Su, Kongzhao; Wu, Mingyan; Tan, Yanxi Chemical Communications, Vol. 53, Issue 69 https://doi.org/10.1039/c7cc05362b	journal	January 2017
Dinuclear zirconium complex bearing a 1,5-bridged-calix[8]arene ligand as an effective catalyst for the synthesis of macrolactones Lapenta, Rosita; De Simone, Nicola Alessandro; Buonerba, Antonio Catalysis Science & Technology, Vol. 8, Issue 10 https://doi.org/10.1039/c7cy02537h	journal	January 2018
Aggregated initiators: defining their role in the ROP of rac -lactide Cols, Jean-Marie E. P.; Hill, Victoria G.; Williams, Stella K. Dalton Transactions, Vol. 47, Issue 31 https://doi.org/10.1039/c8dt01229f	journal	January 2018
Synthesis, crystal structure, and cytotoxicity studies of titanacalix[4 and 8]arene complexes Miller-Shakesby, David M.; Nigam, Shubhanchi; Hughes, David L. Dalton Transactions, Vol. 47, Issue 27 https://doi.org/10.1039/c8dt01992d	journal	January 2018
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