Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations

Migdisov, Artaches; Williams-Jones, A. E.; Brugger, J.; Caporuscio, Florie Andre

doi:10.1016/j.chemgeo.2016.06.005

Title: Hydrothermal transport, deposition, and fractionation of the REE: Experimental data and thermodynamic calculations

Journal Article · Sat Jun 11 00:00:00 EDT 2016 · Chemical Geology

DOI:https://doi.org/10.1016/j.chemgeo.2016.06.005· OSTI ID:1351190

^[1]; Williams-Jones, A. E. ^[2]; Brugger, J. ^[3];

^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
McGill Univ., Montreal, QC (Canada)
Monash Univ., Melbourne, VIC (Australia)

For many years, our understanding of the behavior of the REE in hydrothermal systems was based on semi-empirical estimates involving extrapolation of thermodynamic data obtained at 25 °C. Since then, a substantial body of experimental data has accumulated on the stability of aqueous complexes of the REE. These data have shown that some of the predictions of Haas et al. (1995) are accurate, but others may be in error by several orders of magnitude. However, application of the data in modeling hydrothermal transport and deposition of the REE has been severely hampered by the lack of data on the thermodynamic properties of even the most common REE minerals. The discrepancies between the predictions and experimental determinations of the thermodynamic properties of aqueous REE species, together with the paucity of data on the stability of REE minerals, raise serious questions about the reliability of some models that have been proposed for the hydrothermal mobility of these critical metals. In this contribution, we review a body of high-temperature experimental data collected over the past 15 years on the stability of REE aqueous species and minerals. Using this new thermodynamic dataset, we re-evaluate the mechanisms responsible for hydrothermal transport and deposition of the REE. We also discuss the mechanisms that can result in REE fractionation during their hydrothermal transport and deposition. Here, our calculations suggest that in hydrothermal solutions, the main REE transporting ligands are chloride and sulfate, whereas fluoride, carbonate, and phosphate likely play an important role as depositional ligands. In addition to crystallographic fractionation, which is based on the differing affinity of mineral structures for the REE, our models suggest that the REE can be fractionated hydrothermally due to the differences in the stability of the LREE and HREE as aqueous chloride complexes.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1351190

Report Number(s):: LA-UR-16-21989

Journal Information:: Chemical Geology, Vol. 439, Issue C; ISSN 0009-2541

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 268 works

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The role of hydrothermal processes in concentrating high-field strength elements in the Strange Lake peralkaline complex, northeastern Canada Salvi, Stefano; Williams-Jones, Anthony E. Geochimica et Cosmochimica Acta, Vol. 60, Issue 11 https://doi.org/10.1016/0016-7037(96)00071-3	journal	June 1996
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Determination of SO4β1 for yttrium and the rare earth elements at I = 0.66 m and t = 25°C—implications for YREE solution speciation in sulfate-rich waters Schijf, Johan; Byrne, Robert H. Geochimica et Cosmochimica Acta, Vol. 68, Issue 13 https://doi.org/10.1016/j.gca.2003.12.003	journal	July 2004
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
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Coordination of ions in aqueous solutions of erbium chloride from X-ray diffraction data Smirnov, P. R.; Grechin, O. V. Russian Journal of Coordination Chemistry, Vol. 39, Issue 9 https://doi.org/10.1134/S1070328413090078	journal	August 2013
Preliminary Fluid Inclusion Constraints on Fluid Evolution in the Bayan Obo Fe-REE-Nb Deposit, Inner Mongolia, China Smith, M. P.; Henderson, P. Economic Geology, Vol. 95, Issue 7 https://doi.org/10.2113/gsecongeo.95.7.1371	journal	November 2000
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REY and Trace Element Chemistry of Fluorite from Post-Variscan Hydrothermal Veins in Paleozoic Units of the North German Basin Nadoll, Patrick; Rehm, Meike; Duschl, Florian Geosciences, Vol. 8, Issue 8 https://doi.org/10.3390/geosciences8080283	journal	July 2018
Ion Association in Lanthanide Chloride Solutions Finney, Aaron R.; Lectez, Sébastien; Freeman, Colin L. Chemistry – A European Journal https://doi.org/10.1002/chem.201900945	journal	May 2019
Mineralogical constraints on Nb–REE mineralization of the Zhujiayuan Nb (−REE) deposit in the North Daba Mountain, South Qinling, China Nie, Xiao; Wang, Zongqi; Chen, Lei Geological Journal, Vol. 55, Issue 6 https://doi.org/10.1002/gj.3710	journal	December 2019
Rare Earth Elements in Mineral Deposits: Speciation in Hydrothermal Fluids and Partitioning in Calcite Perry, Emily P.; Gysi, Alexander P. Geofluids, Vol. 2018 https://doi.org/10.1155/2018/5382480	journal	January 2018
The s in Hydrothermal Systems Migdisov, Artaches (Artas); Xu, Hongwu; Williams‐Jones, Anthony E. Encyclopedia of Water: Science, Technology, and Society https://doi.org/10.1002/9781119300762.wsts0079	book	January 2019
Hydrothermal Alteration of Eudialyte-Hosted Critical Metal Deposits: Fluid Source and Implications for Deposit Grade van de Ven, Mathijs A. J.; Borst, Anouk M.; Davies, Gareth R. Minerals, Vol. 9, Issue 7 https://doi.org/10.3390/min9070422	journal	July 2019
Carbonatites: related ore deposits, resources, footprint, and exploration methods Simandl, George J.; Paradis, Suzanne Applied Earth Science, Vol. 127, Issue 4 https://doi.org/10.1080/25726838.2018.1516935	journal	October 2018
Hydrothermal formation of heavy rare earth element (HREE)–xenotime deposits at 100 °C in a sedimentary basin Richter, Lisa; Diamond, Larryn W.; Atanasova, Petya Geology, Vol. 46, Issue 3 https://doi.org/10.1130/g39871.1	journal	January 2018
Critical Elements in Supergene Phosphates: The Example of the Weathering Profile at the Gavà Neolithic Mines, Catalonia, Spain Díaz-Acha, Yael; Campeny, Marc; Tauler, Esperança Minerals, Vol. 10, Issue 1 https://doi.org/10.3390/min10010003	journal	December 2019
Fractionation of Rare Earth Elements in Greisen and Hydrothermal Veins Related to A-Type Magmatism Tillberg, Mikael; Maskenskaya, Olga M.; Drake, Henrik Geofluids, Vol. 2019 https://doi.org/10.1155/2019/4523214	journal	August 2019
Hydrothermal formation of heavy rare earth element (HREE)–xenotime deposits at 100 °C in a sedimentary basin Richter, Lisa; Diamond, Larryn William; Atanasova, Petya Geological Society of America https://doi.org/10.7892/boris.112805	text	January 2018

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