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Title: Sequential infiltration synthesis for advanced lithography

Patent ·
OSTI ID:1350952

A plasma etch resist material modified by an inorganic protective component via sequential infiltration synthesis (SIS) and methods of preparing the modified resist material. The modified resist material is characterized by an improved resistance to a plasma etching or related process relative to the unmodified resist material, thereby allowing formation of patterned features into a substrate material, which may be high-aspect ratio features. The SIS process forms the protective component within the bulk resist material through a plurality of alternating exposures to gas phase precursors which infiltrate the resist material. The plasma etch resist material may be initially patterned using photolithography, electron-beam lithography or a block copolymer self-assembly process.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Number(s):
8,980,418
Application Number:
13/427,619
OSTI ID:
1350952
Resource Relation:
Patent File Date: 2012 Mar 22
Country of Publication:
United States
Language:
English

References (36)

Method of forming high aspect ratio apertures patent January 2007
Complementary replacement of material patent July 2008
Method for manufacturing porous structure and method for forming pattern patent-application October 2006
TRILAYER RESIST SCHEME FOR GATE ETCHING APPLICATIONS patent-application April 2009
Method of Controlling Orientation of Domains in Block Copolymer Films patent-application July 2009
Block Copolymer Lithography: Periodic Arrays of 1011 Holes in 1 Square Centimeter journal May 1997
Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds journal December 2001
UHV transmission electron microscopy on the reconstructed surface of (111) gold: I. General features journal November 1981
PRIME process for deep UV and E-beam lithography journal April 1990
Application of Plasmask R  resist and the DESIRE process to lithography at 248 nm journal November 1990
Approaches to deep ultraviolet photolithography utilizing acid hardened resin photoresist systems
  • Thackeray, James W.; Orsula, George W.; Bohland, John F.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 7, Issue 6, Article No. 1620 https://doi.org/10.1116/1.584502
journal November 1989
Optimized surface silylation of chemically amplified epoxidized photoresists for micromachining applications journal April 2010
Study of the fundamental contributions to line edge roughness in a 193 nm, top surface imaging system
  • Somervell, Mark H.; Fryer, David S.; Osborn, Brian
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 18, Issue 5 https://doi.org/10.1116/1.1289547
journal January 2000
Integrated Silylation and Dry Development of Resist for sub-0.15.MU.m Top Surface Imaging Applications. journal January 1998
Reduction of line edge roughness in the top surface imaging process
  • Mori, Shigeyasu; Morisawa, Taku; Matsuzawa, Nobuyuki
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 16, Issue 6, Article No. 3739 https://doi.org/10.1116/1.590409
journal November 1998
Optical Characterization and Process Control of Top Surface Imaging journal January 1999
High sensitive negative silylation process for 193nm lithography journal June 2000
Enhanced Lithographic Imaging Layer Meets Semiconductor Manufacturing Specification a Decade Early journal April 2012
Nanoscopic Patterned Materials with Tunable Dimensions via Atomic Layer Deposition on Block Copolymers journal September 2010
A Route to Nanoscopic Materials via Sequential Infiltration Synthesis on Block Copolymer Templates journal May 2011
Enhanced Block Copolymer Lithography Using Sequential Infiltration Synthesis journal July 2011
Etch properties of resists modified by sequential infiltration synthesis
  • Tseng, Yu-Chih; Peng, Qing; Ocola, Leonidas E.
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 29, Issue 6, Article No. 06FG01 https://doi.org/10.1116/1.3640758
journal November 2011
Two-Dimensional Liquid Phase and the px.sqroot.3 Phase of Alkanethiol Self-Assembled Monolayers on Au(111) journal October 1994
Effect of thin-film imaging on line edge roughness transfer to underlayers during etch processes
  • Goldfarb, Dario L.; Mahorowala, Arpan P.; Gallatin, Gregg M.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 22, Issue 2 https://doi.org/10.1116/1.1667513
journal January 2004
Plasma-polymer interactions: A review of progress in understanding polymer resist mask durability during plasma etching for nanoscale fabrication
  • Oehrlein, Gottlieb S.; Phaneuf, Raymond J.; Graves, David B.
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 29, Issue 1 https://doi.org/10.1116/1.3532949
journal January 2011
Mobility analysis of surface roughness scattering in FinFET devices journal August 2011
An experimentally validated analytical model for gate line-edge roughness (LER) effects on technology scaling journal June 2001
VDD scalability of FinFET SRAMs: Robustness of different design options against LER-induced variations journal September 2010
Statistical Modeling and Simulation of Threshold Variation Under Random Dopant Fluctuations and Line-Edge Roughness journal June 2011
Line edge roughness of sub-100 nm dense and isolated features: Experimental study
  • Ma, Yuansheng; Tsvid, G.; Cerrina, Franco
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 21, Issue 6 https://doi.org/10.1116/1.1624254
journal January 2003
Study on line edge roughness for electron beam acceleration voltages from 50 to 5 kV
  • Rio, D.; Constancias, C.; Saied, M.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 27, Issue 6 https://doi.org/10.1116/1.3253650
journal January 2009
25 nm mechanically buttressed high aspect ratio zone plates: Fabrication and performance
  • Olynick, Deirdre L.; Harteneck, Bruce D.; Veklerov, Eugene
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 22, Issue 6 https://doi.org/10.1116/1.1815298
journal January 2004
High Precision Etching of Si/SiO[sub 2] on a High-Density Helicon Etcher for Nanoscale Devices journal January 2003
Profile evolution during polysilicon gate etching with low-pressure high-density Cl2/HBr/O2 plasma chemistries
  • Tuda, Mutumi; Shintani, Kenji; Ootera, Hiroki
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 19, Issue 3 https://doi.org/10.1116/1.1365135
journal May 2001
CD characterization of nanostructures in SEM metrology journal January 2007
Hollow Inorganic Nanospheres and Nanotubes with Tunable Wall Thicknesses by Atomic Layer Deposition on Self-Assembled Polymeric Templates journal January 2007