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Title: ANL technical support program for DOE environmental restoration and waste management. Annual report, October 1993--September 1994

Abstract

A program was established for DOE Environmental Restoration and Waste Management (EM) to evaluate factors that are anticipated to affect waste glass reaction during repository disposal, especially in an unsaturated environment typical of what may be expected for the proposed Yucca Mountain repository site. This report covers progress in FY 1994 on the following tasks: (1) Critical Reviews of important parameters that affect the reactivity of glass in an unsaturated environment are being prepared. (2) A series of tests is ongoing to evaluate the reactivity of fully radioactive glasses in a high-level waste repository environment and compare it to the reactivity of synthetic, nonradioactive glasses of similar composition. (3) The effect of radiation upon the durability of waste glasses at a high SA/V ratio and a high gas-to-liquid volume ratio has been assessed. (4) A series of tests is being performed to compare the extent of reaction of nuclear waste glasses at various SA/V ratios. Such differences in the SA/V ratio may significantly affect glass durability. At long-term periods and high SA/V ratios, acceleration in glass reaction has been observed. (5) Tests were initiated on West Valley Reference 6 (WV6) glass and on the Environmental Assessment (EA) glass. (6) Testsmore » with the actinide-doped West Valley glass ATM-10 have been in progress for over seven years as a part of work for the Yucca Mountain Site Characterization Project (YMP). (7) Analytical electron microscopy (AEM) is being used to assess the glass/water reaction pathway by identifying intermediate phases that appear on the reacting glass. Also, colloids from the leach solutions are being studied using AEM.« less

Authors:
; ;  [1]
  1. and others
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE, Washington, DC (United States)
OSTI Identifier:
134998
Report Number(s):
ANL-95/20
ON: DE95016554; TRN: 96:004559
DOE Contract Number:  
W-31109-ENG-38
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: Jun 1995
Country of Publication:
United States
Language:
English
Subject:
05 NUCLEAR FUELS; HIGH-LEVEL RADIOACTIVE WASTES; UNDERGROUND DISPOSAL; VITRIFICATION; RADIOACTIVE WASTE PROCESSING; GLASS; EVALUATION; CHEMICAL REACTIONS; PROGRESS REPORT; RADIOACTIVE WASTE MANAGEMENT; US DOE; ANL; YUCCA MOUNTAIN; Yucca Mountain Project

Citation Formats

Bates, J K, Brown, N R, and Buck, E C. ANL technical support program for DOE environmental restoration and waste management. Annual report, October 1993--September 1994. United States: N. p., 1995. Web. doi:10.2172/134998.
Bates, J K, Brown, N R, & Buck, E C. ANL technical support program for DOE environmental restoration and waste management. Annual report, October 1993--September 1994. United States. https://doi.org/10.2172/134998
Bates, J K, Brown, N R, and Buck, E C. 1995. "ANL technical support program for DOE environmental restoration and waste management. Annual report, October 1993--September 1994". United States. https://doi.org/10.2172/134998. https://www.osti.gov/servlets/purl/134998.
@article{osti_134998,
title = {ANL technical support program for DOE environmental restoration and waste management. Annual report, October 1993--September 1994},
author = {Bates, J K and Brown, N R and Buck, E C},
abstractNote = {A program was established for DOE Environmental Restoration and Waste Management (EM) to evaluate factors that are anticipated to affect waste glass reaction during repository disposal, especially in an unsaturated environment typical of what may be expected for the proposed Yucca Mountain repository site. This report covers progress in FY 1994 on the following tasks: (1) Critical Reviews of important parameters that affect the reactivity of glass in an unsaturated environment are being prepared. (2) A series of tests is ongoing to evaluate the reactivity of fully radioactive glasses in a high-level waste repository environment and compare it to the reactivity of synthetic, nonradioactive glasses of similar composition. (3) The effect of radiation upon the durability of waste glasses at a high SA/V ratio and a high gas-to-liquid volume ratio has been assessed. (4) A series of tests is being performed to compare the extent of reaction of nuclear waste glasses at various SA/V ratios. Such differences in the SA/V ratio may significantly affect glass durability. At long-term periods and high SA/V ratios, acceleration in glass reaction has been observed. (5) Tests were initiated on West Valley Reference 6 (WV6) glass and on the Environmental Assessment (EA) glass. (6) Tests with the actinide-doped West Valley glass ATM-10 have been in progress for over seven years as a part of work for the Yucca Mountain Site Characterization Project (YMP). (7) Analytical electron microscopy (AEM) is being used to assess the glass/water reaction pathway by identifying intermediate phases that appear on the reacting glass. Also, colloids from the leach solutions are being studied using AEM.},
doi = {10.2172/134998},
url = {https://www.osti.gov/biblio/134998}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Jun 01 00:00:00 EDT 1995},
month = {Thu Jun 01 00:00:00 EDT 1995}
}