Gold-supported cerium-doped NiOx catalysts for water oxidation

Ng, Jia Wei Desmond; García-Melchor, Max; Bajdich, Michal; Chakthranont, Pongkarn; Kirk, Charlotte; Vojvodic, Aleksandra; Jaramillo, Thomas F.

doi:10.1038/nenergy.2016.53

Title: Gold-supported cerium-doped NiO_x catalysts for water oxidation

Journal Article · Fri Apr 29 00:00:00 EDT 2016 · Nature Energy

DOI:https://doi.org/10.1038/nenergy.2016.53· OSTI ID:1349410

Ng, Jia Wei Desmond ^[1]; García-Melchor, Max ^[2];

^[2]; Chakthranont, Pongkarn ^[1]; Kirk, Charlotte ^[1]; Vojvodic, Aleksandra ^[2]; Jaramillo, Thomas F. ^[3]

Stanford Univ., Stanford, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Here, the development of high-performance catalysts for the oxygen-evolution reaction (OER) is paramount for cost-effective conversion of renewable electricity to fuels and chemicals. Here we report the significant enhancement of the OER activity of electrodeposited NiO_x films resulting from the combined effects of using cerium as a dopant and gold as a metal support. This NiCeO_x–Au catalyst delivers high OER activity in alkaline media, and is among the most active OER electrocatalysts yet reported. On the basis of experimental observations and theoretical modelling, we ascribe the activity to a combination of electronic, geometric and support effects, where highly active under-coordinated sites at the oxide support interface are modified by the local chemical binding environment and by doping the host Ni oxide with Ce. The NiCeO_x–Au catalyst is further demonstrated in a device context by pairing it with a nickel–molybdenum hydrogen evolution catalyst in a water electrolyser, which delivers 50 mA consistently at 1.5 V over 24 h of continuous operation.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1349410

Journal Information:: Nature Energy, Vol. 1, Issue 5; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 420 works

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Title: Gold-supported cerium-doped NiOx catalysts for water oxidation

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Title: Gold-supported cerium-doped NiO_x catalysts for water oxidation