High-density 3D graphene-based monolith and related materials, methods, and devices

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Charnvanichborikarn, Supakit; Kucheyev, Sergei; Montalvo, Elizabeth; Shin, Swanee; Tylski, Elijah

Title: High-density 3D graphene-based monolith and related materials, methods, and devices

Patent · Tue Mar 21 00:00:00 EDT 2017

OSTI ID:1347564

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; Charnvanichborikarn, Supakit; Kucheyev, Sergei; Montalvo, Elizabeth; Shin, Swanee; Tylski, Elijah

A composition comprising at least one high-density graphene-based monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds and having a density of at least 0.1 g/cm.sup.3. Also provided is a method comprising: preparing a reaction mixture comprising a suspension and at least one catalyst, said suspension selected from a graphene oxide (GO) suspension and a carbon nanotube suspension; curing the reaction mixture to produce a wet gel; drying the wet gel to produce a dry gel, said drying step is substantially free of supercritical drying and freeze drying; and pyrolyzing the dry gel to produce a high-density graphene-based monolith. Exceptional combinations of properties are achieved including high conductive and mechanical properties.

View Patent

Cite

Export

Save

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC52-07NA27344

Assignee:: Lawrence Livermore National Security, LLC

Patent Number(s):: 9,601,226

Application Number:: 13/844,340

OSTI ID:: 1347564

Resource Relation:: Patent File Date: 2013 Mar 15

Country of Publication:: United States

Language:: English

References (84)

Process for preparing monoliths of aerogels of metal oxides Cogliati, Guido; Bezzi, Giovanni https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5207814 US Patent Document 5,207,814	patent	May 1993
Method of manufacturing aerogel composites Cao, Wanqing; Hunt, Arlon J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5879744 US Patent Document 5,879,744	patent	March 1999
Chemical composition Jadesjo, Gunilla; Jonsson, Gustav https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5885953 US Patent Document 5,885,953	patent	March 1999
Storage device and method for sorption and desorption of molecular gas contained by storage sites of nano-filament laded reticulated aerogel Struthers, Ralph C.; Chang, David B.; Toossi, Reza https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7378188 US Patent Document 7,378,188	patent	May 2008
Aerogel and xerogel composites for use as carbon anodes Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7410718 US Patent Document 7,410,718	patent	August 2008
Aerogel and xerogel composites for use as carbon anodes Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7811711 US Patent Document 7,811,711	patent	October 2010
Graphene aerogels Pauzauskie, Peter J.; Worsley, Marcus A.; Baumann, Theodore F. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8993113 US Patent Document 8,993,113	patent	March 2015
Graphene and graphene oxide aerogels Wang, Jian; Ellsworth, Mark W. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100144904 US Patent Application 12/315701; 20100144904	patent-application	June 2010
Mechanically Robust, Electrically Conductive Ultralow-Density Carbon Nanotude-Based Aerogels Worsley, Marcus A.; Kucheyev, Sergei O.; Baumann, Theodore F. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100187484 US Patent Application 12/652616; 20100187484	patent-application	July 2010
Graphene Compositions Scheffer, Dan; Lettow, JOhn; Varma, Vipin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110186786 US Patent Application 12/848152; 20110186786	patent-application	August 2011
Crosslinked Graphene and Graphite Oxide Lettow, John; Scheffer, Dan; Varma, Vipin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110189452 US Patent Application 12/848148; 20110189452	patent-application	August 2011
Graphene Tapes Korkut, Sibel; Milius, David L.; Roy-Mayhew, Joseph D. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110287241 US Patent Application 12/949448; 20110287241	patent-application	November 2011
Graphene Aerogels Pauzauskie, Peter; Worsley, Marcus; Baumann, Theodore https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120034442 US Patent Application 13/204277; 20120034442	patent-application	February 2012
Unitary graphene layer or graphene single crystal Zhamu, Aruna; Wang, Mingchao; Xiong, Wei https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140147648 US Patent Application 13/694356; 20140147648	patent-application	May 2014
Unitary graphene matrix composites containing carbon or graphite fillers Zhamu, Aruna; Wang, Mingchoa; Xiong, Wei https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140154941 US Patent Application 13/694468; 20140154941	patent-application	June 2014
Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels Al-Muhtaseb, S. A.; Ritter, J. A. Advanced Materials, Vol. 15, Issue 2, p. 101-114 https://doi.org/10.1002/adma.200390020	journal	January 2003
Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries Arora, Pankaj; White, Ralph E.; Doyle, Marc Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667 https://doi.org/10.1149/1.1838857	journal	January 1998
Superior Thermal Conductivity of Single-Layer Graphene Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong Nano Letters, Vol. 8, Issue 3, p. 902-907 https://doi.org/10.1021/nl0731872	journal	March 2008
Raman validity for crystallite size L_a determination on reticulated vitreous carbon with different graphitization index Baldan, M. R.; Almeida, E. C.; Azevedo, A. F. Applied Surface Science, Vol. 254, Issue 2, p. 600-603 https://doi.org/10.1016/j.apsusc.2007.06.038	journal	November 2007
Carbon 1s near-edge-absorption fine structure in graphite Batson, P. E. Physical Review B, Vol. 48, Issue 4, p. 2608-2610 https://doi.org/10.1103/PhysRevB.48.2608	journal	July 1993
Facile Synthesis of a Crystalline, High-Surface-Area SnO₂ Aerogel Baumann, T. F.; Kucheyev, S. O.; Gash, A. E. Advanced Materials, Vol. 17, Issue 12, p. 1546-1548 https://doi.org/10.1002/adma.200500074	journal	June 2005
Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition Chen, Zongping; Ren, Wencai; Gao, Libo Nature Materials, Vol. 10, Issue 6, p. 424-428 https://doi.org/10.1038/nmat3001	journal	April 2011
Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite Cote, Laura J.; Cruz-Silva, Rodolfo; Huang, Jiaxing Journal of the American Chemical Society, Vol. 131, Issue 31, p. 11027-11032 https://doi.org/10.1021/ja902348k	journal	August 2009
Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material Eda, Goki; Fanchini, Giovanni; Chhowalla, Manish Nature Nanotechnology, Vol. 3, Issue 5, p. 270-274 https://doi.org/10.1038/nnano.2008.83	journal	April 2008
Interpretation of Raman spectra of disordered and amorphous carbon Ferrari, A. C.; Robertson, J. Physical Review B, Vol. 61, Issue 20, p. 14095-14107 https://doi.org/10.1103/PhysRevB.61.14095	journal	May 2000
Raman Spectrum of Graphene and Graphene Layers Ferrari, A. C.; Meyer, J. C.; Scardaci, V. Physical Review Letters, Vol. 97, Issue 18, Article No. 187401 https://doi.org/10.1103/PhysRevLett.97.187401	journal	October 2006
Practical Chemical Sensors from Chemically Derived Graphene Fowler, Jesse D.; Allen, Matthew J.; Tung, Vincent C. ACS Nano, Vol. 3, Issue 2, p. 301-306 https://doi.org/10.1021/nn800593m	journal	February 2009
Strong Akaganeite Aerogel Monoliths Using Epoxides: Synthesis and Characterization Gash, Alexander E.; Satcher, Joe H.; Simpson, Randall L. Chemistry of Materials, Vol. 15, Issue 17, p. 3268-3275 https://doi.org/10.1021/cm034211p	journal	August 2003
The rise of graphene Geim, A. K.; Novoselov, K. S. Nature Materials, Vol. 6, Issue 3, p. 183-191 https://doi.org/10.1038/nmat1849	journal	March 2007
Extremely high thermal conductivity of graphene: Prospects for thermal management applications in nanoelectronic circuits Ghosh, S.; Calizo, I.; Teweldebrhan, D. Applied Physics Letters, Vol. 92, Issue 15, Article No. 151911 https://doi.org/10.1063/1.2907977	journal	April 2008
Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets Gomez-Navarro, Cristina; Weitz, R. Thomas; Bittner, Alexander M. Nano Letters, Vol. 7, Issue 11, p. 3499-3503 https://doi.org/10.1021/nl072090c	journal	November 2007
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene Graf, D.; Molitor, F.; Ensslin, K. Nano Letters, Vol. 7, Issue 2, p. 238-242 https://doi.org/10.1021/nl061702a	journal	February 2007
Adsorption Surface Area and Porosity Gregg, S. J.; Sing, K. S. W.; Salzberg, H. W. Journal of The Electrochemical Society, Vol. 114, Issue 11, p. 279C https://doi.org/10.1149/1.2426447	journal	January 1967
Binder-Free and Carbon-Free Nanoparticle Batteries: A Method for Nanoparticle Electrodes without Polymeric Binders or Carbon Black Ha, Don-Hyung; Islam, Mohammad A.; Robinson, Richard D. Nano Letters, Vol. 12, Issue 10, p. 5122-5130 https://doi.org/10.1021/nl3019559	journal	September 2012
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Carrier Transport in Two-Dimensional Graphene Layers Hwang, E. H.; Adam, S.; Sarma, S. Das Physical Review Letters, Vol. 98, Issue 18, Article No. 186806 https://doi.org/10.1103/PhysRevLett.98.186806	journal	May 2007
Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe₂O₃Compound Jain, Gaurav; Balasubramanian, Mahalingam; Xu, Jun John Chemistry of Materials, Vol. 18, Issue 2, p. 423-434 https://doi.org/10.1021/cm052014f	journal	January 2006
X-ray absorption spectroscopy of graphite oxide Jeong, H.-K.; Noh, H.-J.; Kim, J.-Y. EPL (Europhysics Letters), Vol. 82, Issue 6, Article No. 67004 https://doi.org/10.1209/0295-5075/82/67004	journal	June 2008
Comment on “Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene” Jeong, H.-K.; Noh, H.-J.; Kim, J.-Y. Physical Review Letters, Vol. 102, Issue 9, Article No. 099701 https://doi.org/10.1103/PhysRevLett.102.099701	journal	March 2009
Depth-sensing indentation of low-density brittle nanoporous solids Kucheyev, S. O.; Hamza, A. V.; Satcher Jr., J. H. Acta Materialia, Vol. 57, Issue 12, p. 3472-3480 https://doi.org/10.1016/j.actamat.2009.04.003	journal	July 2009
In situ infrared observation of the pyrolysis process of carbon aerogels Kuhn, J.; Brandt, R.; Mehling, H. Journal of Non-Crystalline Solids, Vol. 225, p. 58-63 https://doi.org/10.1016/S0022-3093(98)00009-X	journal	April 1998
Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe₂O₃ with Various Particle Sizes Larcher, D.; Bonnin, D.; Cortes, R. Journal of The Electrochemical Society, Vol. 150, Issue 12, p. A1643-A1650 https://doi.org/10.1149/1.1622959	journal	January 2003
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential Laruelle, S.; Grugeon, S.; Poizot, P. Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634 https://doi.org/10.1149/1.1467947	journal	January 2002
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene Lee, C.; Wei, X.; Kysar, J. W. Science, Vol. 321, Issue 5887, p. 385-388 https://doi.org/10.1126/science.1157996	journal	July 2008
Highly conducting graphene sheets and Langmuir–Blodgett films Li, Xiaolin; Zhang, Guangyu; Bai, Xuedong Nature Nanotechnology, Vol. 3, Issue 9, p. 538-542 https://doi.org/10.1038/nnano.2008.210	journal	August 2008
A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films Liu, Fei; Seo, Tae Seok Advanced Functional Materials, Vol. 20, Issue 12, p. 1930-1936 https://doi.org/10.1002/adfm.201000287	journal	May 2010
Thermal and electrical conductivity of monolithic carbon aerogels Lu, Xianping; Nilsson, Ove; Fricke, Jochen Journal of Applied Physics, Vol. 73, Issue 2, p. 581-584 https://doi.org/10.1063/1.353367	journal	January 1993
Core excitons and vibronic coupling in diamond and graphite Ma, Y.; Skytt, P.; Wassdahl, N. Physical Review Letters, Vol. 71, Issue 22, p. 3725-3728 https://doi.org/10.1103/PhysRevLett.71.3725	journal	November 1993
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H. Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404 https://doi.org/10.1021/cm0630800	journal	September 2007
Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells Morales, Julian; Sanchez, Luis; Martin, Francisco Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1748-A1754 https://doi.org/10.1149/1.1972812	journal	January 2005
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S. Science, Vol. 306, Issue 5696, p. 666-669 https://doi.org/10.1126/science.1102896	journal	October 2004
An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments Oliver, W. C.; Pharr, G. M. Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583 https://doi.org/10.1557/JMR.1992.1564	journal	June 1992
Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene Pacile, D.; Papagno, M.; Rodríguez, A. Fraile Physical Review Letters, Vol. 101, Issue 6, Article No. 066806 https://doi.org/10.1103/PhysRevLett.101.066806	journal	August 2008
Specific surface area of carbon nanotubes and bundles of carbon nanotubes Peigney, A.; Laurent, Ch.; Flahaut, E. Carbon, Vol. 39, Issue 4, p. 507-514 https://doi.org/10.1016/S0008-6223(00)00155-X	journal	April 2001
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Poizot, P.; Laruelle, S.; Grugeon, S. Nature, Vol. 407, Issue 6803, p. 496-499 https://doi.org/10.1038/35035045	journal	September 2000
Functionalized graphene sheets for polymer nanocomposites Ramanathan, T.; Abdala, A. A.; Stankovich, S. Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331 https://doi.org/10.1038/nnano.2008.96	journal	May 2008
Detection of individual gas molecules adsorbed on graphene Schedin, F.; Geim, A. K.; Morozov, S. V. Nature Materials, Vol. 6, Issue 9, p. 652-655 https://doi.org/10.1038/nmat1967	journal	July 2007
Graphene Based Electrochemical Sensors and Biosensors: A Review Shao, Yuyan; Wang, Jun; Wu, Hong Electroanalysis, Vol. 22, Issue 10, p. 1027-1036 https://doi.org/10.1002/elan.200900571	journal	March 2010
Graphene-based composite materials Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B. Nature, Vol. 442, Issue 7100, p. 282-286 https://doi.org/10.1038/nature04969	journal	July 2006
Epitaxial graphene on ruthenium Sutter, Peter W.; Flege, Jan-Ingo; Sutter, Eli A. Nature Materials, Vol. 7, Issue 5, p. 406-411 https://doi.org/10.1038/nmat2166	journal	April 2008
Structure and electronic properties of a nongraphitic disordered carbon system and its heat-treatment effects Takai, Kazuyuki; Oga, Meigo; Sato, Hirohiko Physical Review B, Vol. 67, Issue 21, Article No. 214202 https://doi.org/10.1103/PhysRevB.67.214202	journal	June 2003
Noble-Metal-Promoted Three-Dimensional Macroassembly of Single-Layered Graphene Oxide Tang, Zhihong; Shen, Shuling; Zhuang, Jing Angewandte Chemie International Edition, Vol. 49, Issue 27, p. 4603-4607 https://doi.org/10.1002/anie.201000270	journal	May 2010
Functionalized graphene sheet filled silicone foam nanocomposites Verdejo, Raquel; Barroso-Bujans, Fabienne; Rodriguez-Perez, Miguel Angel Journal of Materials Chemistry, Vol. 18, Issue 19, p. 2221-2226 https://doi.org/10.1039/b718289a	journal	January 2008
Fabrication of Graphene-Polymer Nanocomposites With Higher-Order Three-Dimensional Architectures Vickery, Jemma L.; Patil, Avinash J.; Mann, Stephen Advanced Materials, Vol. 21, Issue 21, p. 2180-2184 https://doi.org/10.1002/adma.200803606	journal	June 2009
Graphene-based electrochemical supercapacitors Vivekchand, S. R. C.; Rout, Chandra Sekhar; Subrahmanyam, K. S. Journal of Chemical Sciences, Vol. 120, Issue 1, p. 9-13 https://doi.org/10.1007/s12039-008-0002-7	journal	January 2008
Electronic and structural properties of graphene-based transparent and conductive thin film electrodes Vollmer, A.; Feng, X. L.; Wang, X. Applied Physics A, Vol. 94, Issue 1, p. 1-4 https://doi.org/10.1007/s00339-008-4931-2	journal	October 2008
Graphene Aerogels Wang, Jian; Ellsworth, Mark https://doi.org/10.1149/1.3119548	conference	January 2009
Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Wang, Hailiang; Cui, Li-Feng; Yang, Yuan Journal of the American Chemical Society, Vol. 132, Issue 40, p. 13978-13980 https://doi.org/10.1021/ja105296a	journal	October 2010
Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage Wang, Donghai; Kou, Rong; Choi, Daiwon ACS Nano, Vol. 4, Issue 3, p. 1587-1595 https://doi.org/10.1021/nn901819n	journal	March 2010
Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells Wang, Xuan; Zhi, Linjie; Müllen, Klaus Nano Letters, Vol. 8, Issue 1, p. 323-327 https://doi.org/10.1021/nl072838r	journal	January 2008
High Surface Area, sp²-Cross-Linked Three-Dimensional Graphene Monoliths Worsley, Marcus A.; Olson, Tammy Y.; Lee, Jonathan R. I. The Journal of Physical Chemistry Letters, Vol. 2, Issue 8, p. 921-925 https://doi.org/10.1021/jz200223x	journal	April 2011
Mechanically robust and electrically conductive carbon nanotube foams Worsley, Marcus A.; Kucheyev, Sergei O.; Satcher, Joe H. Applied Physics Letters, Vol. 94, Issue 7, Article No. 073115 https://doi.org/10.1063/1.3086293	journal	February 2009
Properties of single-walled carbon nanotube-based aerogels as a function of nanotube loading Worsley, Marcus A.; Pauzauskie, Peter J.; Kucheyev, Sergei O. Acta Materialia, Vol. 57, Issue 17, p. 5131-5136 https://doi.org/10.1016/j.actamat.2009.07.012	journal	October 2009
Stiff and electrically conductive composites of carbon nanotube aerogels and polymers Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D. Journal of Materials Chemistry, Vol. 19, Issue 21, p. 3370-3372 https://doi.org/10.1039/b905735h	journal	January 2009
Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide–Carbon Nanotube Composites Worsley, Marcus A.; Kucheyev, Sergei O.; Kuntz, Joshua D. Chemistry of Materials, Vol. 23, Issue 12, p. 3054-3061 https://doi.org/10.1021/cm200426k	journal	June 2011
Synthesis of Graphene Aerogel with High Electrical Conductivity Worsley, Marcus A.; Pauzauskie, Peter J.; Olson, Tammy Y. Journal of the American Chemical Society, Vol. 132, Issue 40, p. 14067-14069 https://doi.org/10.1021/ja1072299	journal	October 2010
Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance Wu, Zhong-Shuai; Ren, Wencai; Wen, Lei ACS Nano, Vol. 4, Issue 6, p. 3187-3194 https://doi.org/10.1021/nn100740x	journal	June 2010
Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation Wu, Zhong-Shuai; Ren, Wencai; Gao, Libo ACS Nano, Vol. 3, Issue 2, p. 411-417 https://doi.org/10.1021/nn900020u	journal	February 2009
Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process Xu, Yuxi; Sheng, Kaixuan; Li, Chun ACS Nano, Vol. 4, Issue 7, p. 4324-4330 https://doi.org/10.1021/nn101187z	journal	July 2010
Assembly of Graphene Sheets into 3D Macroscopic Structures Yin, Shengyan; Niu, Zhiqiang; Chen, Xiaodong Small, Vol. 8, Issue 16, p. 2458-2463 https://doi.org/10.1002/smll.201102614	journal	May 2012
Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji Nano Letters, Vol. 8, Issue 8, p. 2277-2282 https://doi.org/10.1021/nl800957b	journal	August 2008
Graphene-Wrapped Fe₃O₄ Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries Zhou, Guangmin; Wang, Da-Wei; Li, Feng Chemistry of Materials, Vol. 22, Issue 18, p. 5306-5313 https://doi.org/10.1021/cm101532x	journal	September 2010
Nanostructured Reduced Graphene Oxide/Fe₂O₃ Composite As a High-Performance Anode Material for Lithium Ion Batteries Zhu, Xianjun; Zhu, Yanwu; Murali, Shanthi ACS Nano, Vol. 5, Issue 4, p. 3333-3338 https://doi.org/10.1021/nn200493r	journal	April 2011
Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel Zu, Sheng-Zhen; Han, Bao-Hang The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13651-13657 https://doi.org/10.1021/jp9035887	journal	August 2009

Similar Records

High-density carbon nanotube-based monolith and related materials, methods, and devices

Patent · Tue Jul 03 00:00:00 EDT 2018 · OSTI ID:1347564

Worsley, Marcus A.; Baumann, Theodore F.; Biener, Juergen; +5 more

Highly crystalline 3D graphene

Patent · Tue Mar 19 00:00:00 EDT 2019 · OSTI ID:1347564

Worsley, Marcus A.; Woo, Leta; Mickelson, William; +1 more

Graphene aerogels

Patent · Tue Mar 31 00:00:00 EDT 2015 · OSTI ID:1347564

Pauzauskie, Peter J; Worsley, Marcus A; Baumann, Theodore F; +2 more

Related Subjects

36 MATERIALS SCIENCE

Title: High-density 3D graphene-based monolith and related materials, methods, and devices

Citation Formats

References (84)

Similar Records

Related Subjects