Roles of Fullerene-Based Interlayers in Enhancing the Performance of Organometal Perovskite Thin-Film Solar Cells

Liang, Po-Wei; Chueh, Chu-Chen; Williams, Spencer T.; Jen, Alex K. -Y.

doi:10.1002/aenm.201402321

Title: Roles of Fullerene-Based Interlayers in Enhancing the Performance of Organometal Perovskite Thin-Film Solar Cells

Journal Article · Fri Feb 27 00:00:00 EST 2015 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201402321· OSTI ID:1343575

Liang, Po-Wei ^[1]; Chueh, Chu-Chen ^[1]; Williams, Spencer T. ^[1]; Jen, Alex K. -Y. ^[2]

Univ. of Washington, Seattle, WA (United States). Dept. of Materials Science and Engineering
Univ. of Washington, Seattle, WA (United States). Dept. of Materials Science and Engineering; Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry

Roles of fullerene-based interlayers in enhancing the performance of organometal perovskite thin-film solar cells are elucidated. By studying various fullerenes, a clear correlation between the electron mobility of fullerenes and the resulting performance of derived devices is determined. The metallic characteristics of the bilayer perovskite/fullerene field-effect transistor indicates an effective charge redistribution occurring at the corresponding interface. Lastly, a conventional perovskite thin-film solar cell derived from the C₆₀ electron-transporting layer (ETL) affords a high power conversion efficiency of 15.4%.

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Research Organization:: Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); US Department of the Navy, Office of Naval Research (ONR); Asian Office of Aerospace R&D; Boeing–Johnson Foundation; National Science Foundation (NSF)

Grant/Contract Number:: EE0006710; N00014–14–1–0170; FA2386–11–1–4072; DGE-1256082

OSTI ID:: 1343575

Report Number(s):: DOE-UW-Jen-10

Journal Information:: Advanced Energy Materials, Vol. 5, Issue 10; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 223 works

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References (43)

Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Interface engineering of highly efficient perovskite solar cells Zhou, H.; Chen, Q.; Li, G. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1254050	journal	July 2014
Solar cell efficiency tables (version 39): Solar cell efficiency tables (version 39) Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro Progress in Photovoltaics: Research and Applications, Vol. 20, Issue 1 https://doi.org/10.1002/pip.2163	journal	December 2011
Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells Eperon, Giles E.; Burlakov, Victor M.; Docampo, Pablo Advanced Functional Materials, Vol. 24, Issue 1, p. 151-157 https://doi.org/10.1002/adfm.201302090	journal	September 2013
Perovskite-Based Hybrid Solar Cells Exceeding 10% Efficiency with High Reproducibility Using a Thin Film Sandwich Approach Conings, Bert; Baeten, Linny; De Dobbelaere, Christopher Advanced Materials, Vol. 26, Issue 13, p. 2041-2046 https://doi.org/10.1002/adma.201304803	journal	December 2013
Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process Chen, Qi; Zhou, Huanping; Hong, Ziruo Journal of the American Chemical Society, Vol. 136, Issue 2, p. 622-625 https://doi.org/10.1021/ja411509g	journal	December 2013
Efficient and stable CH3NH3PbI3-sensitized ZnO nanorod array solid-state solar cells Bi, Dongqin; Boschloo, Gerrit; Schwarzmüller, Stefan Nanoscale, Vol. 5, Issue 23 https://doi.org/10.1039/c3nr01542d	journal	January 2013
Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques Liu, Dianyi; Kelly, Timothy L. Nature Photonics, Vol. 8, Issue 2, p. 133-138 https://doi.org/10.1038/nphoton.2013.342	journal	December 2013
Low-temperature processed meso-superstructured to thin-film perovskite solar cells Ball, James M.; Lee, Michael M.; Hey, Andrew Energy & Environmental Science, Vol. 6, Issue 6 https://doi.org/10.1039/c3ee40810h	journal	January 2013
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Efficient planar heterojunction perovskite solar cells by vapour deposition Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J. Nature, Vol. 501, Issue 7467, p. 395-398 https://doi.org/10.1038/nature12509	journal	September 2013
Enhancing the Hole-Conductivity of Spiro-OMeTAD without Oxygen or Lithium Salts by Using Spiro(TFSI) ₂ in Perovskite and Dye-Sensitized Solar Cells Nguyen, William H.; Bailie, Colin D.; Unger, Eva L. Journal of the American Chemical Society, Vol. 136, Issue 31 https://doi.org/10.1021/ja504539w	journal	July 2014
The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells Sun, Shuangyong; Salim, Teddy; Mathews, Nripan Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE43161D	journal	January 2014
Perovskite solar cells employing organic charge-transport layers Malinkiewicz, Olga; Yella, Aswani; Lee, Yong Hui Nature Photonics, Vol. 8, Issue 2 https://doi.org/10.1038/nphoton.2013.341	journal	December 2013
CH ₃ NH ₃ PbI ₃ Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells Jeng, Jun-Yuan; Chiang, Yi-Fang; Lee, Mu-Huan Advanced Materials, Vol. 25, Issue 27 https://doi.org/10.1002/adma.201301327	journal	June 2013
Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates Docampo, Pablo; Ball, James M.; Darwich, Mariam Nature Communications, Vol. 4, Article No. 2761 https://doi.org/10.1038/ncomms3761	journal	November 2013
Nickel Oxide Electrode Interlayer in CH ₃ NH ₃ PbI ₃ Perovskite/PCBM Planar-Heterojunction Hybrid Solar Cells Jeng, Jun-Yuan; Chen, Kuo-Cheng; Chiang, Tsung-Yu Advanced Materials, Vol. 26, Issue 24 https://doi.org/10.1002/adma.201306217	journal	March 2014
Sequential Deposition of CH ₃ NH ₃ PbI ₃ on Planar NiO Film for Efficient Planar Perovskite Solar Cells Hu, Long; Peng, Jun; Wang, Weiwei ACS Photonics, Vol. 1, Issue 7 https://doi.org/10.1021/ph5000067	journal	June 2014
High-Performance and Environmentally Stable Planar Heterojunction Perovskite Solar Cells Based on a Solution-Processed Copper-Doped Nickel Oxide Hole-Transporting Layer Kim, Jong H.; Liang, Po-Wei; Williams, Spencer T. Advanced Materials, Vol. 27, Issue 4 https://doi.org/10.1002/adma.201404189	journal	November 2014
Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen Advanced Materials, Vol. 26, Issue 22, p. 3748-3754 https://doi.org/10.1002/adma.201400231	journal	March 2014
Low-Temperature Solution-Processed Perovskite Solar Cells with High Efficiency and Flexibility You, Jingbi; Hong, Ziruo; Yang, Yang (Michael) ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn406020d	journal	January 2014
Benefits of very thin PCBM and LiF layers for solution-processed p–i–n perovskite solar cells Seo, Jangwon; Park, Sangman; Chan Kim, Young Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE01216J	journal	January 2014
Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process Wang, Qi; Shao, Yuchuan; Dong, Qingfeng Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00233D	journal	January 2014
Planar heterojunction perovskite/PC ₇₁ BM solar cells with enhanced open-circuit voltage via a (2/1)-step spin-coating process Chiang, Chien-Hung; Tseng, Zong-Liang; Wu, Chun-Guey J. Mater. Chem. A, Vol. 2, Issue 38 https://doi.org/10.1039/C4TA03674C	journal	January 2014
Energy Level Alignment and Interfacial Electronic Structures at Organic/Metal and Organic/Organic Interfaces Ishii, Hisao; Sugiyama, Kiyoshi; Ito, Eisuke Advanced Materials, Vol. 11, Issue 8, p. 605-625 https://doi.org/10.1002/(SICI)1521-4095(199906)11:8<605::AID-ADMA605>3.0.CO;2-Q	journal	June 1999
Electron Energetics at Surfaces and Interfaces: Concepts and Experiments Cahen, D.; Kahn, A. Advanced Materials, Vol. 15, Issue 4 https://doi.org/10.1002/adma.200390065	journal	February 2003
Separating Charges at Organic Interfaces: Effects of Disorder, Hot States, and Electric Field Nayak, Pabitra K.; Narasimhan, K. L.; Cahen, David The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz4002339	journal	May 2013
Evaluation of structure–property relationships of solution-processible fullerene acceptors and their n-channel field-effect transistor performance Li, Chang-Zhi; Chueh, Chu-Chen; Yip, Hin-Lap Journal of Materials Chemistry, Vol. 22, Issue 30 https://doi.org/10.1039/c2jm32693k	journal	January 2012
High-Performance Planar-Heterojunction Solar Cells Based on Ternary Halide Large-Band-Gap Perovskites Liang, Po-Wei; Chueh, Chu-Chen; Xin, Xu-Kai Advanced Energy Materials, Vol. 5, Issue 1 https://doi.org/10.1002/aenm.201400960	journal	August 2014
The roles of alkyl halide additives in enhancing perovskite solar cell performance Chueh, Chu-Chen; Liao, Chien-Yi; Zuo, Fan Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05012F	journal	January 2015
Binary-Metal Perovskites Toward High-Performance Planar-Heterojunction Hybrid Solar Cells Zuo, Fan; Williams, Spencer T.; Liang, Po-Wei Advanced Materials, Vol. 26, Issue 37 https://doi.org/10.1002/adma.201401641	journal	August 2014
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
Anomalous Hysteresis in Perovskite Solar Cells Snaith, Henry J.; Abate, Antonio; Ball, James M. The Journal of Physical Chemistry Letters, Vol. 5, Issue 9 https://doi.org/10.1021/jz500113x	journal	April 2014
Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers Xiao, Zhengguo; Bi, Cheng; Shao, Yuchuan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE01138D	journal	January 2014
Enhanced Photoluminescence and Solar Cell Performance via Lewis Base Passivation of Organic–Inorganic Lead Halide Perovskites Noel, Nakita K.; Abate, Antonio; Stranks, Samuel D. ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn5036476	journal	September 2014
Supramolecular Halogen Bond Passivation of Organic–Inorganic Halide Perovskite Solar Cells Abate, Antonio; Saliba, Michael; Hollman, Derek J. Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl500627x	journal	May 2014
Origin and elimination of photocurrent hysteresis by fullerene passivation in CH3NH3PbI3 planar heterojunction solar cells Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6784	journal	December 2014
Doping of Fullerenes via Anion-Induced Electron Transfer and Its Implication for Surfactant Facilitated High Performance Polymer Solar Cells Li, Chang-Zhi; Chueh, Chu-Chen; Ding, Feizhi Advanced Materials, Vol. 25, Issue 32 https://doi.org/10.1002/adma.201300580	journal	June 2013
Solution-Processible Highly Conducting Fullerenes Li, Chang-Zhi; Chueh, Chu-Chen; Yip, Hin-Lap Advanced Materials, Vol. 25, Issue 17, p. 2457-2461 https://doi.org/10.1002/adma.201204543	journal	March 2013

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C ₆₀ additive-assisted crystallization in CH ₃ NH ₃ Pb _0.75 Sn _0.25 I ₃ perovskite solar cells with high stability and efficiency Liu, Chong; Li, Wenzhe; Li, Hongliang Nanoscale, Vol. 9, Issue 37 https://doi.org/10.1039/c7nr03507a	journal	January 2017
A stable, efficient textile-based flexible perovskite solar cell with improved washable and deployable capabilities for wearable device applications Lam, Jeun-Yan; Chen, Jung-Yao; Tsai, Ping-Chun RSC Advances, Vol. 7, Issue 86 https://doi.org/10.1039/c7ra10321b	journal	January 2017
A dimeric fullerene derivative for efficient inverted planar perovskite solar cells with improved stability Tian, Chengbo; Kochiss, Kevin; Castro, Edison Journal of Materials Chemistry A, Vol. 5, Issue 16 https://doi.org/10.1039/c7ta00362e	journal	January 2017
Recent advances in perovskite solar cells: efficiency, stability and lead-free perovskite Yang, Shida; Fu, Weifei; Zhang, Zhongqiang Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/c7ta00366h	journal	January 2017
Progress in fullerene-based hybrid perovskite solar cells Castro, Edison; Murillo, Jesse; Fernandez-Delgado, Olivia Journal of Materials Chemistry C, Vol. 6, Issue 11 https://doi.org/10.1039/c7tc04302c	journal	January 2018
Spray coating of the PCBM electron transport layer significantly improves the efficiency of p-i-n planar perovskite solar cells Zheng, Yifan; Kong, Jaemin; Huang, Di Nanoscale, Vol. 10, Issue 24 https://doi.org/10.1039/c8nr01763h	journal	January 2018
Influence of doped charge transport layers on efficient perovskite solar cells Avila, Jorge; Gil-Escrig, Lidon; Boix, Pablo P. Sustainable Energy & Fuels, Vol. 2, Issue 11 https://doi.org/10.1039/c8se00218e	journal	January 2018
Restrained light-soaking and reduced hysteresis in perovskite solar cells employing a helical perylene diimide interfacial layer Yang, Liyan; Wu, Mingliang; Cai, Feilong Journal of Materials Chemistry A, Vol. 6, Issue 22 https://doi.org/10.1039/c8ta02584c	journal	January 2018
Achieving high-performance thick-film perovskite solar cells with electron transporting Bingel fullerenes Yan, Kangrong; Chen, Jiehuan; Ju, Huanxin Journal of Materials Chemistry A, Vol. 6, Issue 32 https://doi.org/10.1039/c8ta05636f	journal	January 2018
Incorporating deep electron traps into perovskite devices: towards high efficiency solar cells and fast photodetectors Zhang, Dezhong; Liu, Chunyu; Li, Zhiqi Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/c8ta08499h	journal	January 2018
Multifunctional asymmetrical molecules for high-performance perovskite and organic solar cells Gao, Wei; Wu, Fei; Liu, Tao Journal of Materials Chemistry A, Vol. 7, Issue 5 https://doi.org/10.1039/c8ta10975c	journal	January 2019
Ballistic transport simulation of acceptor–donor C ₃ N/C ₃ B double-wall hetero-nanotube field effect transistors Zhao, Jianwei; Cheng, Na; He, Yuanyuan Physical Chemistry Chemical Physics, Vol. 21, Issue 35 https://doi.org/10.1039/c9cp03456k	journal	January 2019
Impact of charge transport layers on the photochemical stability of MAPbI ₃ in thin films and perovskite solar cells Boldyreva, A. G.; Akbulatov, A. F.; Elnaggar, M. Sustainable Energy & Fuels, Vol. 3, Issue 10 https://doi.org/10.1039/c9se00493a	journal	January 2019
Highly efficient flexible MAPbI ₃ solar cells with a fullerene derivative-modified SnO ₂ layer as the electron transport layer Zhong, Meiyan; Liang, Yongqi; Zhang, Jianqi Journal of Materials Chemistry A, Vol. 7, Issue 12 https://doi.org/10.1039/c9ta00398c	journal	January 2019
N,P-coordinated fullerene-like carbon nanostructures with dual active centers toward highly-efficient multi-functional electrocatalysis for CO ₂ RR, ORR and Zn-air battery Xue, Xiaoyi; Yang, Hui; Yang, Tao Journal of Materials Chemistry A, Vol. 7, Issue 25 https://doi.org/10.1039/c9ta03828k	journal	January 2019
Structural and electronic properties of multifunctional carbon composites of organometal halide perovskites Klejna, Sylwia Journal of Materials Chemistry A, Vol. 7, Issue 43 https://doi.org/10.1039/c9ta06517b	journal	January 2019
Perovskite solar cell-hybrid devices: thermoelectrically, electrochemically, and piezoelectrically connected power packs Zabihi, Fatemeh; Tebyetekerwa, Mike; Xu, Zhen Journal of Materials Chemistry A, Vol. 7, Issue 47 https://doi.org/10.1039/c9ta08070h	journal	January 2019
High-performance inverted planar perovskite solar cells using a pristine fullerene mixture as an electron-transport layer Xu, Chongyang; Liu, Zhihai; Lee, Eun-Cheol Journal of Materials Chemistry C, Vol. 7, Issue 23 https://doi.org/10.1039/c9tc01741k	journal	January 2019
The effect of hole transporting layer in charge accumulation properties of p-i-n perovskite solar cells Galatopoulos, Fedros; Savva, Achilleas; Papadas, Ioannis T. APL Materials, Vol. 5, Issue 7 https://doi.org/10.1063/1.4991030	journal	July 2017
Understanding the impact of C ₆₀ at the interface of perovskite solar cells via drift-diffusion modeling Golubev, Timofey; Liu, Dianyi; Lunt, Richard AIP Advances, Vol. 9, Issue 3 https://doi.org/10.1063/1.5068690	journal	March 2019
Recent advances in interfacial engineering of perovskite solar cells Ye, Meidan; He, Chunfeng; Iocozzia, James Journal of Physics D: Applied Physics, Vol. 50, Issue 37 https://doi.org/10.1088/1361-6463/aa7cb0	journal	August 2017
Possible interfacial ion/charge accumulation in thin-film perovskite/fullerene surfactant planar heterojunction solar cells Liang, Po-Wei; Chen, Chih-I; Chueh, Chu-Chen Journal of Physics D: Applied Physics, Vol. 51, Issue 50 https://doi.org/10.1088/1361-6463/aaddde	journal	September 2018
First-principles calculation of stability, electronic and optical properties of PCBM-adsorbed MAPbI ₃ surface Tian, Ying; Xue, Hongtao; Tang, Fuling Materials Research Express, Vol. 6, Issue 11 https://doi.org/10.1088/2053-1591/ab51dc	journal	September 2019
Hysteresis Passivation in Planar Perovskite Solar Cells Utilizing Facile Chemical Vapor Deposition Process and PCBM Interlayer Yang, Chongqiu; Shan, Xiaobiao; Xie, Tao Energies, Vol. 12, Issue 23 https://doi.org/10.3390/en12234508	journal	November 2019
Efficient Regular Perovskite Solar Cells Based on Pristine [70]Fullerene as Electron-Selective Contact Collavini, Silvia; Kosta, Ivet; Völker, Sebastian F. ChemSusChem, Vol. 9, Issue 11 https://doi.org/10.1002/cssc.201600684	journal	June 2016
Versatility of Carbon Enables All Carbon Based Perovskite Solar Cells to Achieve High Efficiency and High Stability Meng, Xiangyue; Zhou, Junshuai; Hou, Jie Advanced Materials, Vol. 30, Issue 36 https://doi.org/10.1002/adma.201804637	journal	September 2018
Nonradiative Recombination in Perovskite Solar Cells: The Role of Interfaces Wolff, Christian M.; Caprioglio, Pietro; Stolterfoht, Martin FID GEO https://doi.org/10.23689/fidgeo-4816	text	January 2019
The Effect of Hole Transporting Layer in Charge Accumulation Properties of p-i-n Perovskite Solar Cells Galatopoulos, Fedros; Savva, Achilleas; Papadas, Ioannis T. arXiv https://doi.org/10.48550/arxiv.1807.07308	text	January 2018
Highly Efficient Reproducible Perovskite Solar Cells Prepared by Low-Temperature Processing Hu, Hao; Wong, Ka; Kollek, Tom Molecules, Vol. 21, Issue 4 https://doi.org/10.3390/molecules21040542	journal	April 2016

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