Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates

Bisogni, Valentina; Catalano, Sara; Green, Robert J.; Gibert, Marta; Scherwitzl, Raoul; Huang, Yaobo; Strocov, Vladimir N.; Zubko, Pavlo; Balandeh, Shadi; Triscone, Jean-Marc; Sawatzky, George; Schmitt, Thorsten

doi:10.1038/ncomms13017

Title: Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates

Journal Article · Tue Oct 11 00:00:00 EDT 2016 · Nature Communications

DOI:https://doi.org/10.1038/ncomms13017· OSTI ID:1341699

Bisogni, Valentina ^[1]; Catalano, Sara ^[2]; Green, Robert J. ^[3]; Gibert, Marta ^[4]; Scherwitzl, Raoul ^[4]; Huang, Yaobo ^[5]; Strocov, Vladimir N. ^[6]; Zubko, Pavlo ^[7]; Balandeh, Shadi ^[8]; Triscone, Jean-Marc ^[4]; Sawatzky, George ^[3]; Schmitt, Thorsten ^[6]

Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Univ. of Geneva (Switzerland). Dept. of Quantum Matter Physics
Univ. of British Columbia, Vancouver, BC (Canada). Dept. of Physics and Astronomy; Univ. of British Columbia, Vancouver, BC (Canada). Quantum Matter Inst.
Univ. of Geneva (Switzerland). Dept. of Quantum Matter Physics
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology; Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics, and Inst. of Physics
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Research Dept. Synchrotron Radiation and Nanotechnology
Univ. of Geneva (Switzerland). Dept. of Quantum Matter Physics; University College London, London (United Kingdom). London Centre for Nanotechnology and Dept. of Physics and Astronomy
Univ. of British Columbia, Vancouver, BC (Canada). Dept. of Physics and Astronomy

The metal-insulator transitions and the intriguing physical properties of rare-earth perovskite nickelates have attracted considerable attention in recent years. However, a complete understanding of these materials remains elusive. Here, taking a NdNiO₃ thin film as a representative example, we utilize a combination of x-ray absorption (XAS) and resonant inelastic x-ray scattering (RIXS) spectroscopies to resolve important aspects of the complex electronic structure of the rare-earth nickelates. The unusual coexistence of bound and continuum excitations observed in the RIXS spectra provides strong evidence for the abundance of oxygen 2p holes in the ground state of these materials. Using cluster calculations and Anderson impurity model interpretation, we show that these distinct spectral signatures arise from a Ni 3d⁸ configuration along with holes in the oxygen 2p valence band, confirming suggestions that these materials do not obey a “conventional” positive charge-transfer picture, but instead exhibit a negative charge-transfer energy, in line with recent models interpreting the metal to insulator transition in terms of bond disproportionation.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1341699

Report Number(s):: BNL-113446-2017-JA

Journal Information:: Nature Communications, Vol. 7; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 144 works

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References (58)

Structural, magnetic and electronic properties of perovskites (R = rare earth) Medarde, María Luisa Journal of Physics: Condensed Matter, Vol. 9, Issue 8 https://doi.org/10.1088/0953-8984/9/8/003	journal	February 1997
Systematic study of insulator-metal transitions in perovskites RNiO3 (R=Pr,Nd,Sm,Eu) due to closing of charge-transfer gap Torrance, J.; Lacorre, P.; Nazzal, A. Physical Review B, Vol. 45, Issue 14 https://doi.org/10.1103/PhysRevB.45.8209	journal	April 1992
Progress in perovskite nickelate research Catalan, G. Phase Transitions, Vol. 81, Issue 7-8 https://doi.org/10.1080/01411590801992463	journal	July 2008
Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M. Nature Physics, Vol. 10, Issue 4 https://doi.org/10.1038/nphys2907	journal	March 2014
Sudden Appearance of an Unusual Spin Density Wave At the Metal-Insulator Transition in the Perovskites RNiO ₃ (R = Pr, Nd) García-Muñoz, J. L.; Rodríguez-Carvajal, J.; Lacorre, P. Europhysics Letters (EPL), Vol. 20, Issue 3 https://doi.org/10.1209/0295-5075/20/3/009	journal	October 1992
Charge Disproportionation in $R {NiO}_{3}$ Perovskites: Simultaneous Metal-Insulator and Structural Transition in ${YNiO}_{3}$ Alonso, J. A.; García-Muñoz, J. L.; Fernández-Díaz, M. T. Physical Review Letters, Vol. 82, Issue 19 https://doi.org/10.1103/PhysRevLett.82.3871	journal	May 1999
Heterointerface engineered electronic and magnetic phases of NdNiO3 thin films Liu, Jian; Kargarian, Mehdi; Kareev, Mikhail Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3714	journal	November 2013
Electric-Field Control of the Metal-Insulator Transition in Ultrathin NdNiO3 Films Scherwitzl, Raoul; Zubko, Pavlo; Lezama, I. Gutierrez Advanced Materials, Vol. 22, Issue 48 https://doi.org/10.1002/adma.201003241	journal	October 2010
Metal-Insulator Transition in Ultrathin ${LaNiO}_{3}$ Films Scherwitzl, R.; Gariglio, S.; Gabay, M. Physical Review Letters, Vol. 106, Issue 24 https://doi.org/10.1103/PhysRevLett.106.246403	journal	June 2011
Low-dimensional Mott material: Transport in ultrathin epitaxial LaNiO3 films Son, Junwoo; Moetakef, Pouya; LeBeau, James M. Applied Physics Letters, Vol. 96, Issue 6 https://doi.org/10.1063/1.3309713	journal	February 2010
Orbital Order and Possible Superconductivity in ${LaNiO}_{3} / {LaMO}_{3}$ Superlattices Chaloupka, Jiří; Khaliullin, Giniyat Physical Review Letters, Vol. 100, Issue 1 https://doi.org/10.1103/PhysRevLett.100.016404	journal	January 2008
Exchange bias in LaNiO3–LaMnO3 superlattices Gibert, Marta; Zubko, Pavlo; Scherwitzl, Raoul Nature Materials, Vol. 11, Issue 3 https://doi.org/10.1038/nmat3224	journal	January 2012
Asymmetric Orbital-Lattice Interactions in Ultrathin Correlated Oxide Films Chakhalian, J.; Rondinelli, J. M.; Liu, Jian Physical Review Letters, Vol. 107, Issue 11 https://doi.org/10.1103/PhysRevLett.107.116805	journal	September 2011
Strain and composition dependence of orbital polarization in nickel oxide superlattices Wu, M.; Benckiser, E.; Haverkort, M. W. Physical Review B, Vol. 88, Issue 12 https://doi.org/10.1103/PhysRevB.88.125124	journal	September 2013
Orbital reflectometry of oxide heterostructures Benckiser, Eva; Haverkort, Maurits W.; Brück, Sebastian Nature Materials, Vol. 10, Issue 3 https://doi.org/10.1038/nmat2958	journal	February 2011
Band gaps and electronic structure of transition-metal compounds Zaanen, J.; Sawatzky, G. A.; Allen, J. W. Physical Review Letters, Vol. 55, Issue 4 https://doi.org/10.1103/PhysRevLett.55.418	journal	July 1985
R ${NiO}_{3}$ perovskites ( R =Pr,Nd): Nickel valence and the metal-insulator transition investigated by x-ray-absorption spectroscopy Medarde, M.; Fontaine, A.; García-Muñoz, J. L. Physical Review B, Vol. 46, Issue 23 https://doi.org/10.1103/PhysRevB.46.14975	journal	December 1992
Electronic structure of ${PrNiO}_{3}$ studied by photoemission and x-ray-absorption spectroscopy: Band gap and orbital ordering Mizokawa, T.; Fujimori, A.; Arima, T. Physical Review B, Vol. 52, Issue 19 https://doi.org/10.1103/PhysRevB.52.13865	journal	November 1995
Electronic structure and metal-insulator transition in ${LaNiO}_{3 - δ}$ Abbate, M.; Zampieri, G.; Prado, F. Physical Review B, Vol. 65, Issue 15 https://doi.org/10.1103/PhysRevB.65.155101	journal	March 2002
Electronic structure of $La Ni O_{3 - x}$ : An in situ soft x-ray photoemission and absorption study Horiba, K.; Eguchi, R.; Taguchi, M. Physical Review B, Vol. 76, Issue 15 https://doi.org/10.1103/PhysRevB.76.155104	journal	October 2007
Origin of the band gap in the negative charge-transfer-energy compound ${NaCuO}_{2}$ Mizokawa, T.; Namatame, H.; Fujimori, A. Physical Review Letters, Vol. 67, Issue 12 https://doi.org/10.1103/PhysRevLett.67.1638	journal	September 1991
Low-energy description of the metal-insulator transition in the rare-earth nickelates Subedi, Alaska; Peil, Oleg E.; Georges, Antoine Physical Review B, Vol. 91, Issue 7 https://doi.org/10.1103/PhysRevB.91.075128	journal	February 2015
Role of magnetic and orbital ordering at the metal-insulator transition in ${NdNiO}_{3}$ Scagnoli, V.; Staub, U.; Mulders, A. M. Physical Review B, Vol. 73, Issue 10 https://doi.org/10.1103/PhysRevB.73.100409	journal	March 2006
Charge Ordering as Alternative to Jahn-Teller Distortion Mazin, I. I.; Khomskii, D. I.; Lengsdorf, R. Physical Review Letters, Vol. 98, Issue 17 https://doi.org/10.1103/PhysRevLett.98.176406	journal	April 2007
Charge disproportionation in $R {NiO}_{3}$ perovskites ( $R = rare$ earth) from high-resolution x-ray absorption spectroscopy Medarde, M.; Dallera, C.; Grioni, M. Physical Review B, Vol. 80, Issue 24 https://doi.org/10.1103/PhysRevB.80.245105	journal	December 2009
Direct Observation of Charge Order in an Epitaxial ${NdNiO}_{3}$ Film Staub, U.; Meijer, G. I.; Fauth, F. Physical Review Letters, Vol. 88, Issue 12 https://doi.org/10.1103/PhysRevLett.88.126402	journal	March 2002
Electric-field tuning of the metal-insulator transition in ultrathin films of LaNiO3 Scherwitzl, R.; Zubko, P.; Lichtensteiger, C. Applied Physics Letters, Vol. 95, Issue 22 https://doi.org/10.1063/1.3269591	journal	November 2009
Magnetic and electronic properties of RNiO ₃ (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction Bodenthin, Y.; Staub, U.; Piamonteze, C. Journal of Physics: Condensed Matter, Vol. 23, Issue 3 https://doi.org/10.1088/0953-8984/23/3/036002	journal	January 2011
Evolution of electronic structure across the rare-earth RNiO3 series Freeland, John W.; van Veenendaal, Michel; Chakhalian, Jak Journal of Electron Spectroscopy and Related Phenomena, Vol. 208 https://doi.org/10.1016/j.elspec.2015.07.006	journal	April 2016
Resonant inelastic x-ray scattering spectra for electrons in solids Kotani, Akio; Shin, Shik Reviews of Modern Physics, Vol. 73, Issue 1 https://doi.org/10.1103/RevModPhys.73.203	journal	February 2001
Resonant inelastic x-ray scattering studies of elementary excitations Ament, Luuk J. P.; van Veenendaal, Michel; Devereaux, Thomas P. Reviews of Modern Physics, Vol. 83, Issue 2 https://doi.org/10.1103/RevModPhys.83.705	journal	June 2011
Electronic structure studies of $V_{6} O_{13}$ by soft x-ray emission spectroscopy: Band-like and excitonic vanadium states Schmitt, T.; Duda, L. -C.; Matsubara, M. Physical Review B, Vol. 69, Issue 12 https://doi.org/10.1103/PhysRevB.69.125103	journal	March 2004
Localized and delocalized Ti 3 $d$ carriers in LaAlO $_{3}$ /SrTiO $_{3}$ superlattices revealed by resonant inelastic x-ray scattering Zhou, Ke-Jin; Radovic, Milan; Schlappa, Justine Physical Review B, Vol. 83, Issue 20 https://doi.org/10.1103/PhysRevB.83.201402	journal	May 2011
NiO as a test case for high resolution resonant inelastic soft x-ray scattering Ghiringhelli, G.; Matsubara, M.; Dallera, C. Journal of Physics: Condensed Matter, Vol. 17, Issue 35 https://doi.org/10.1088/0953-8984/17/35/007	journal	August 2005
Optical spectroscopy of the metal-insulator transition in ${NdNiO}_{3}$ Katsufuji, T.; Okimoto, Y.; Arima, T. Physical Review B, Vol. 51, Issue 8 https://doi.org/10.1103/PhysRevB.51.4830	journal	February 1995
Mott Physics near the Insulator-To-Metal Transition in ${NdNiO}_{3}$ Stewart, M. K.; Liu, Jian; Kareev, M. Physical Review Letters, Vol. 107, Issue 17 https://doi.org/10.1103/PhysRevLett.107.176401	journal	October 2011
Tuning the metal-insulator transition in ${NdNiO}_{3}$ heterostructures via Fermi surface instability and spin fluctuations Dhaka, R. S.; Das, Tanmoy; Plumb, N. C. Physical Review B, Vol. 92, Issue 3 https://doi.org/10.1103/PhysRevB.92.035127	journal	July 2015
Orbital Engineering in Nickelate Heterostructures Driven by Anisotropic Oxygen Hybridization rather than Orbital Energy Levels Fabbris, G.; Meyers, D.; Okamoto, J. Physical Review Letters, Vol. 117, Issue 14 https://doi.org/10.1103/PhysRevLett.117.147401	journal	September 2016
Intra- versus inter-site electronic excitations in NdNiO3 by resonant inelastic ultra-soft X-ray scattering at Ni 3p edge Butorin, S. M.; Såthe, C.; Agui, A. Solid State Communications, Vol. 135, Issue 11-12 https://doi.org/10.1016/j.ssc.2005.06.006	journal	September 2005
Ordering and criticality in an underscreened Kondo chain Ko, Wing-Ho; Jiang, Hong-Chen; Rau, Jeffrey G. Physical Review B, Vol. 87, Issue 20 https://doi.org/10.1103/PhysRevB.87.205107	journal	May 2013
Key role of lattice symmetry in the metal-insulator transition of NdNiO3 films Zhang, Jack Y.; Kim, Honggyu; Mikheev, Evgeny Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23652	journal	April 2016
High-resolution soft X-ray beamline ADRESS at the Swiss Light Source for resonant inelastic X-ray scattering and angle-resolved photoelectron spectroscopies Strocov, V. N.; Schmitt, T.; Flechsig, U. Journal of Synchrotron Radiation, Vol. 17, Issue 5 https://doi.org/10.1107/S0909049510019862	journal	July 2010
SAXES, a high resolution spectrometer for resonant x-ray emission in the 400–1600eV energy range Ghiringhelli, G.; Piazzalunga, A.; Dallera, C. Review of Scientific Instruments, Vol. 77, Issue 11 https://doi.org/10.1063/1.2372731	journal	November 2006
Asymmetric orbital-lattice interactions in ultra-thin correlated oxide films Chakhalian, J.; Rondinelli, J. M.; Liu, Jian arXiv https://doi.org/10.48550/arxiv.1008.1373	text	January 2010
Origins of bad metal conductivity and the insulator-metal transition in the rare-earth nickelates Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M. arXiv https://doi.org/10.48550/arxiv.1309.7394	text	January 2013
Heterointerface engineered electronic and magnetic phases of NdNiO3 thin films Liu, Jian; Kargarian, Mehdi; Kareev, Mikhail arXiv https://doi.org/10.48550/arxiv.1311.4611	text	January 2013
Evolution of Electronic Structure Across the Rare-Earth RNiO$_3$ Series Freeland, John W.; van Veenendaal, Michel; Chakhalian, Jak arXiv https://doi.org/10.48550/arxiv.1504.02802	preprint	January 2015
Tuning the metal-insulator transition in NdNiO3 heterostructures via Fermi surface instability and spin-fluctuations Dhaka, R. S.; Das, Tanmoy; Plumb, N. C. arXiv https://doi.org/10.48550/arxiv.1505.04510	text	January 2015
Orbital engineering in nickelate heterostructures driven by anisotropic oxygen hybridization rather than orbital energy levels Fabbris, G.; Meyers, D.; Okamoto, J. arXiv https://doi.org/10.48550/arxiv.1603.08873	text	January 2016
Spin and charge ordering in self-doped Mott insulators Mizokawa, T.; Khomskii, D. I.; Sawatzky, G. A. arXiv https://doi.org/10.48550/arxiv.cond-mat/9908016	text	January 1999
Anomalous variation of phonon Raman intensities near the metal-to-Mott-insulator transition in titanium oxide systems Katsufuji, T.; Tokura, Y. Physical Review B, Vol. 50, Issue 4 https://doi.org/10.1103/physrevb.50.2704	journal	July 1994
Spin and charge ordering in self-doped Mott insulators Mizokawa, T.; Khomskii, D. I.; Sawatzky, G. A. Physical Review B, Vol. 61, Issue 17 https://doi.org/10.1103/physrevb.61.11263	journal	May 2000
Observation of Two Nondispersive Magnetic Excitations in NiO by Resonant Inelastic Soft-X-Ray Scattering Ghiringhelli, G.; Piazzalunga, A.; Dallera, C. Physical Review Letters, Vol. 102, Issue 2 https://doi.org/10.1103/physrevlett.102.027401	journal	January 2009
Ultrafast Strain Engineering in Complex Oxide Heterostructures Caviglia, A. D.; Scherwitzl, R.; Popovich, P. Physical Review Letters, Vol. 108, Issue 13 https://doi.org/10.1103/physrevlett.108.136801	journal	March 2012
Metal-Insulator Transition and Orbital Reconstruction in Mott-Type Quantum Wells Made of ${NdNiO}_{3}$ Liu, Jian; Kareev, M.; Meyers, D. Physical Review Letters, Vol. 109, Issue 10 https://doi.org/10.1103/physrevlett.109.107402	journal	September 2012
Theory of the Magnetic and Metal-Insulator Transitions in $R {NiO}_{3}$ Bulk and Layered Structures Lau, Bayo; Millis, Andrew J. Physical Review Letters, Vol. 110, Issue 12 https://doi.org/10.1103/physrevlett.110.126404	journal	March 2013
Charge Disproportionation without Charge Transfer in the Rare-Earth-Element Nickelates as a Possible Mechanism for the Metal-Insulator Transition Johnston, Steve; Mukherjee, Anamitra; Elfimov, Ilya Physical Review Letters, Vol. 112, Issue 10 https://doi.org/10.1103/physrevlett.112.106404	journal	March 2014
Orbital Engineering in Symmetry-Breaking Polar Heterostructures Disa, Ankit S.; Kumah, Divine P.; Malashevich, Andrei Physical Review Letters, Vol. 114, Issue 2 https://doi.org/10.1103/physrevlett.114.026801	journal	January 2015

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Site-Selective Probe of Magnetic Excitations in Rare-Earth Nickelates Using Resonant Inelastic X-ray Scattering Lu, Y.; Betto, D.; Fürsich, K. Physical Review X, Vol. 8, Issue 3 https://doi.org/10.1103/physrevx.8.031014	journal	July 2018
Factors Controlling the Redox Activity of Oxygen in Perovskites: From Theory to Application for Catalytic Reactions Yang, Chunzhen; Grimaud, Alexis Catalysts, Vol. 7, Issue 5 https://doi.org/10.3390/catal7050149	journal	May 2017
High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3 Zheng, Hong; Zhang, Junjie; Wang, Bixia Crystals, Vol. 9, Issue 7 https://doi.org/10.3390/cryst9070324	journal	June 2019
Complex magnetic order in nickelate slabs Hepting, M.; Green, R. J.; Zhong, Z. Nature Publishing Group https://doi.org/10.5167/uzh-158586	text	January 2018
High-resolution resonant inelastic extreme ultraviolet scattering from orbital and spin excitations in a Heisenberg antiferromagnet Caretta, Antonio; Dell'Angela, Martina; Chuang, Yi-De Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-00296	text	January 2017
Site-Selective Probe of Magnetic Excitations in Rare-Earth Nickelates Using Resonant Inelastic X-ray Scattering Lu, Y.; Betto, D.; Fürsich, K. Karlsruhe https://doi.org/10.5445/ir/1000084863	text	January 2018
Transmission zone plates as analyzers for efficient parallel 2D RIXS-mapping Marschall, Felix; Yin, Zhong; Rehanek, Jens Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2017-09548	text	January 2017
Electronic localization in CaVO3 films via bandwidth control McNally, Daniel E.; Lu, Xingye; Pelliciari, Jonathan ETH Zurich https://doi.org/10.3929/ethz-b-000325574	text	January 2019
Bond disproportionation and dynamical charge fluctuations in the perovskite rare earth nickelates Green, Robert J.; Haverkort, Maurits W.; Sawatzky, George A. arXiv https://doi.org/10.48550/arxiv.1608.01645	text	January 2016
Mott Transition and Magnetism in Rare Earth Nickelates and its Fingerprint on the X-ray Scattering Haule, Kristjan; Pascut, Gheorghe L. arXiv https://doi.org/10.48550/arxiv.1703.08196	text	January 2017
Electronic structure of Pr2MnNiO6 from x-ray photoemission, absorption and density functional theory Balasubramanian, Padmanabhan; Joshi, Shalik Ram; Yadav, Ruchika arXiv https://doi.org/10.48550/arxiv.1710.08617	text	January 2017
Continuum Charge Excitations in High-Valence Transition-Metal Oxides Revealed by Resonant Inelastic X-ray Scattering Hariki, Atsushi; Winder, Mathias; Kuneš, Jan arXiv https://doi.org/10.48550/arxiv.1803.03820	text	January 2018
Phenomenological Three-Orbital Spin-Fermion Model for Cuprates Hussein, Mostafa Sherif Derbala Aly; Daghofer, Maria; Dagotto, Elbio arXiv https://doi.org/10.48550/arxiv.1804.07191	text	January 2018
Emergent c-axis magnetic helix in manganite-nickelate superlattices Fabbris, G.; Jaouen, N.; Meyers, D. arXiv https://doi.org/10.48550/arxiv.1806.04775	text	January 2018
Epitaxial strain modulated electronic properties of interface controlled nickelate superlattice Middey, S.; Meyers, D.; Ojha, Shashank Kumar arXiv https://doi.org/10.48550/arxiv.1807.00449	text	January 2018
Fingerprints of an Exotic Orbital-Selective Mott Phase in the Block Magnetic State of BaFe$_2$Se$_3$ Ladders Patel, Niravkumar D.; Nocera, Alberto; Alvarez, Gonzalo arXiv https://doi.org/10.48550/arxiv.1807.10419	text	January 2018
Complex magnetic order in nickelate slabs Hepting, Matthias; Green, Robert J.; Zhong, Zhicheng arXiv https://doi.org/10.48550/arxiv.1905.04160	text	January 2019
High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3 Zheng, Hong; Zhang, Junjie; Wang, Bixia arXiv https://doi.org/10.48550/arxiv.1907.00078	text	January 2019
Conductivity noise across temperature driven transitions of rare-earth nickelate heterostructures Daptary, Gopi Nath; Kumar, Siddharth; Kareev, M. arXiv https://doi.org/10.48550/arxiv.1908.06413	text	January 2019
Electronic Localization in CaVO3 Films via Bandwidth Control McNally, Daniel E.; Lu, Xingye; Pelliciari, Jonathan arXiv https://doi.org/10.48550/arxiv.1908.10604	text	January 2019
Electronic structure of the parent compound of superconducting infinite-layer nickelates Hepting, M.; Li, D.; Jia, C. J. arXiv https://doi.org/10.48550/arxiv.1909.02678	text	January 2019
Finite-temperature phase diagram of (111) nickelate bilayers Janson, Oleg; Held, Karsten Physical Review B, Vol. 98, Issue 11 https://doi.org/10.1103/physrevb.98.115118	journal	September 2018
Observation of an antiferromagnetic quantum critical point in high-purity LaNiO$_3$ Liu, Changjiang; Humbert, Vincent F. C.; Bretz-Sullivan, Terence arXiv https://doi.org/10.48550/arxiv.2002.04159	text	January 2020

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